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| Name |
Dicyclohexylammonium nitrite |
EINECS | 221-515-9 | |
| CAS No. | 3129-91-7 | Density | 0.91g/cm3 | |
| PSA | 61.69000 | LogP | 3.77430 | |
| Solubility | 39 g/l (soluble in alcohols) | Melting Point |
182 - 183 C (Decomposes) |
|
| Formula | C12H23N.HNO2 | Boiling Point | 256.1°Cat760mmHg | |
| Molecular Weight | 228.335 | Flash Point | 100 C | |
| Transport Information | 268 | Appearance | white powder | |
| Safety | Poison by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data. A flammable liquid. When heated to decomposition it emits very toxic fumes of HNO2 and NOx. See also NITRITES. | Risk Codes | 20/22 | |
| Molecular Structure |
|
Hazard Symbols | 4.1 (Packing Group: III) UN NO. | |
| Synonyms |
Dichan;VP 1260;NDA (corrosion inhibitor);VPI 260;Diana (corrosion inhibitor);Leukorrosin C;TVI;N-cyclohexylcyclohexanamine; nitrous acid;Cyclohexanamine,N-cyclohexyl-,nitrite;DICYCLOHEXYLAMINE NITRITE;DODECAHYDROPHENYLAMINE NITRITE;DUSITAN DICYKLOHEXYLAMINU (CZECH);DECHAN;DICHAN (CZECH);DICYCLOHEXYL-AMINONITRITE;DICYNIT (CZECH);DICYKLOHEXYLAMIN NITRIT (CZECH);N,N-Dicyclohexylammonium nitrite; |
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Dicyclohexylammonium nitrite Synthetic route
- 3129-91-7
dicyclohexylamine nitrite
A
- 64-19-7
acetic acid
B
- 802294-64-0
propionic acid
C
- 79-31-2
isobutyric Acid
D
- 107-92-6
butyric acid
E
- 109-52-4
valeric acid
| Conditions | Yield |
|---|---|
| With ozone In water at 40℃; for 1.16667h; Product distribution; diff. concentrations of O3; diff. reaction time; influence of alkaline; |
Dicyclohexylammonium nitrite Chemical Properties
Product Name: Dicyclohexylammonium nitrite (CAS NO.3129-91-7)
Molecular Formula: C12H24N2O2
Molecular Weight: 228.33g/mol
Mol File: 3129-91-7.mol
Einecs: 221-515-9
Appearance: White to light-colored crystalline solid
Melting Point: 188-194 °C (dec.)
Boiling point: 256.1 °C at 760 mmHg
Flash Point: 96.1 °C
Enthalpy of Vaporization: 49.36 kJ/mol
Vapour Pressure: 0.0157 mmHg at 25°C
H-Bond Donor: 2
H-Bond Acceptor: 4
Product Categories: Pharmaceutical Intermediates; Intermediates of Dyes and Pigments; Aromatic Esters
Dicyclohexylammonium nitrite Uses
Dicyclohexylammonium nitrite (CAS NO.3129-91-7) can be used as vapor phase corrosion inhibitor. It is mainly used for metal corrosion protection and to prevent metal corrosion to continue. Eg for motor vehicles and parts, deceleration chassis, internal combustion engines, machine tools, cutting tools measuring tools, etc. can also be used in weapons, radar and other equipment of the metal protection. Vapor corrosion inhibitor with excellent performance, long period of anti-rust, anti-rust effect is good, complex and simple components are suitable. But it was brass, tin and its alloys are corrosion.
Dicyclohexylammonium nitrite Production
Dicyclohexylammonium nitrite (CAS NO.3129-91-7) consists of dicyclohexylamine reaction with phosphoric acid dicyclohexylamine, and then adding sodium nitrite dicyclohexylamine nitrite reaction: reaction products after washing and drying was finished.
Dicyclohexylammonium nitrite Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | oral | 50mg/kg (50mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 50, 1982. | |
| guinea pig | LD50 | oral | 350mg/kg (350mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) | University of California, Berkeley, Publications in Pharmacology. Vol. 2, Pg. 231, 1949. |
| mouse | LC | inhalation | > 90mg/m3/4H (90mg/m3) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965. | |
| mouse | LD50 | oral | 80mg/kg (80mg/kg) | BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965. |
| mouse | LD50 | subcutaneous | 155mg/kg (155mg/kg) | Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. Vol. 4, Pg. 659, 1958. Link to PubMed | |
| mouse | LD50 | unreported | 220mg/kg (220mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972. | |
| rabbit | LD50 | unreported | 375mg/kg (375mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972. | |
| rat | LC | inhalation | > 90mg/m3/4H (90mg/m3) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965. | |
| rat | LD50 | oral | 330mg/kg (330mg/kg) | LIVER: OTHER CHANGES BLOOD: NORMOCYTIC ANEMIA | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 29(11), Pg. 51, 1985. |
| rat | LD50 | unreported | 565mg/kg (565mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972. | |
| rat | LDLo | skin | 2gm/kg (2000mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 50, 1982. |
Dicyclohexylammonium nitrite Consensus Reports
Reported in EPA TSCA Inventory.
Dicyclohexylammonium nitrite Safety Profile
Poison by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data. A flammable liquid. When heated to decomposition it emits very toxic fumes of HNO2 and NOx. See also NITRITES.
Safety Information of Dicyclohexylammonium nitrite (CAS NO.3129-91-7):
Hazard Codes: Xn.gif){kind=small}
Risk Statements: 20/22
20: Harmful by inhalation
22: Harmful if swallowed
Dicyclohexylammonium nitrite Standards and Recommendations
DOT Classification: 4.1; Label: Flammable Solid
Dicyclohexylammonium nitrite Specification
Dicyclohexylammonium nitrite,its CAS NO. is 3129-91-7,the synonyms is Nitrous acid dicyclohexylamine ; n,n-Dicyclohexylammonium nitrite ; Dicyclohexylamine nitrite ; Dicyclohexylammonium nitrite ; Dodecahydrodiphenylamine nitrite ; Biscyclohexylaminenitrite ; Cyclohexanamine, n-cyclohexyl-, nitrite ; Cyclohexanamine,n-cyclohexyl-,nitrite .
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