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Iron(II) EDTA complex

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Name

Iron(II) EDTA complex

EINECS N/A
CAS No. 21393-59-9 Density N/A
PSA 161.34000 LogP -4.74310
Solubility N/A Melting Point N/A
Formula C10H12 Fe N2 O8 . 2 H Boiling Point N/A
Molecular Weight 346.077 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx. See also IRON COMPOUNDS. Risk Codes N/A
Molecular Structure Molecular Structure of 21393-59-9 (Ferrate(2-),[[N,N'-1,2-ethanediylbis[N-[(carboxy-kO)methyl]glycinato-kN,kO]](4-)]-, hydrogen (1:2), (OC-6-21)-) Hazard Symbols N/A
Synonyms

Ferrate(2-),[(ethylenedinitrilo)tetraacetato]-, dihydrogen (8CI); Ferrate(2-),[[N,N'-1,2-ethanediylbis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']-,dihydrogen, (OC-6-21)-; Ferrate(2-), [[N,N'-1,2-ethanediylbis[N-[(carboxy-kO)methyl]glycinato-kN,kO]](4-)]-, dihydrogen, (OC-6-21)- (9CI); Hydrogen[(ethylenedinitrilo)tetraacetato]ferrate(II) (6CI,7CI); Dihydrogen[ethylenediaminetetraacetato(4-)]ferrate(2-); Ferrous EDTA; Ferrousethylenediaminetetraacetate; Fetrilon; Iron EDTA; Ironethylenediaminetetraacetate; Iron(II) EDTA; Sequestrene H 2FE; [Dihydrogen(ethylenedinitrilo)tetraacetato]iron

Article Data 16

Iron(II) EDTA complex Synthetic route

iron(II) chloride tetrahydrate

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
With citrate buffer In water stoich. amt. of Fe-salt addn. to deaerated Na-salt soln. buffered at pH 4.8;

iron(II) sulfate

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water prepared in the absence of O2;;

iron(II) chloride

A

21393-59-9

iron(II) ethylenediaminetetraacetate

B

Fe(II)(Hedta)

Conditions
ConditionsYield
In water product ratio depending on pH;;

iron(II) ethylenediaminetetraacetic acid*NO

A

21393-59-9

iron(II) ethylenediaminetetraacetate

B

[Fe(ethylenediaminetetraacetate)](1-)

C

10102-43-9

nitrogen(II) oxide

Conditions
ConditionsYield
With borax; potassium dihydrogenphosphate; sodium sulfite In water Kinetics; at various temps. and over pH range of 5.74-8.00, ionic strength adjusted with KCl, pH controlled with buffer soln., equilibrium react.; detected by UV absorption;

iron(III) ammonium sulfate dodecahydrate

disodium ethylenediaminetetraacetate dihydrate

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water Kinetics; byproducts: Fe2O3, ethylenediaminetriacetic acid, iminodiacetic acid; 1:1.5 ratio of Fe(III) to EDTA in H2O heated at 175°C at pH 9.3 (NaOH or NH3 controll) under inert atm.; Fe2O3 filtered, product detected by NMR, if 1:1 ratio of reagents used Fe2O3 formed;

Ammonium iron sulfate

disodium ethylenediaminetetraacetate dihydrate

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water
In water Hodges, H. L., Holwerda, R. A., Gray, H. B., J. Am. Chem. Soc., 1974, 98, 3132; through aq. soln. of Na2H2(EDTA)*2H2O bubbled N2 for 1 h, addedair-free (NH4)2Fe(SO4)2*6H2O; not isolated from soln.;

ferrous(II) sulfate heptahydrate

60-00-4

ethylenediaminetetraacetic acid

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water reaction in deoxygenized solns.;
19052-44-9

hexaamineruthenium(II)

[Fe(ethylenediaminetetraacetate)](1-)

A

18943-33-4

hexaammineruthenium(III)

B

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water Kinetics; soln. of Fe complex, 0.10 M TrisH(1+), 0.90 M NaClO4 (or LiClO4) adjusted with HClO4 (pH 4.5-6.5), soln. of Ru complex, 0.1 M TrisH(1+), 0.9 MNaClO4 adjusted with HCl; at 5.0-35.0 °C; not isolated, monitored by UV;

[Fe(ethylenediaminetetraacetate)](1-)

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
With sodium sulfide In water Kinetics; byproducts: Fe(OH)EDTA, Fe(OH)2EDTA, S; reaction at 23°C in an aq. alkaline soln. of Na2S (0.76E-3, 1.52E-3, 3.04E-3, 6.08E-3 or 12.16E-3 M), FeEDTA: 0.11E-3 M at pH = 8; existence of an intermediate complex discussed; variation of pH discussed;; detn. of the change of optical density (depending on time) at 500 nm;;
With ethanethiol In water Kinetics; byproducts: C2H5SSC2H5, Fe(OH)EDTA, Fe(OH)2EDTA; reaction at 14°C, pH = 9.0 with an excess of FeEDTA(1-) (7.67E-2 M); concentration of C2H5SH 0.0075, 0.00568 or 0.00372 M in a glass reactor (apparatus described);; determination of the change of optical density (depending on time) at 540 .+-. 10 nm;;
With ethanethiol In water Kinetics; byproducts: C2H5SSC2H5, Fe(OH)EDTA, Fe(OH)2EDTA; reaction at 21°C, pH = 9.0 with an excess of C2H5SH (0.0198 M); concentration of FeEDTA(1-) 0.005, 0.0025, 0.00125 or 0.625E-3 M in a closed cuvette; variation of pH discussed; formation of an intermediate complex discussed;; determination of the change of optical density (depending on time) at 540 .+-. 10 nm;;
With sodium sulfide In water Kinetics; byproducts: Fe(OH)EDTA, Fe(OH)2EDTA, S; reaction at 23°C in an aq. alkaline soln. of Na2S (2.8E-3 M), FeEDTA: 0.22E-3 M at pH = 8 in presence of sulfur (0.3E-4, 0.6E-4, 1.2E-4, 2.4E-4 or 4.8E-4 M); existence of an intermediate complex discussed; variation of pH discussed;; detn. of the change of optical density (depending on time) at 500 nm;;

ferrous ammonium sulphate

21393-59-9

iron(II) ethylenediaminetetraacetate

Conditions
ConditionsYield
In water a potassium salt of EDTA was dissolved in H2O at pH 7, Fe-salt was added;

Iron(II) EDTA complex Chemical Properties

Empirical Formula of Iron(II) EDTA complex (CAS NO.21393-59-9): C10H14FeN2O8
Molecular Weight: 346.0718 g/mol
EINECS: 244-356-7
Flash Point: 325.2 °C
Enthalpy of Vaporization: 99.5 kJ/mol
Boiling Point: 614.2 °C at 760 mmHg
Vapour Pressure: 1.15E-16 mmHg at 25 °C
Structure of Iron(II) EDTA complex (CAS NO.21393-59-9):
                          
IUPAC Name: 2-[2-[Bis(2-oxido-2-oxoethyl)amino]ethyl-(2-oxido-2-oxoethyl)amino]acetate ; Hydron ; Iron(2+)
Canonical SMILES: [H+].[H+].C(CN(CC(=O)[O-])CC(=O)[O-])N(CC(=O)[O-])CC(=O)[O-].[Fe+2]
InChI: InChI=1S/C10H16N2O8.Fe/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)
20;/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20);/q;+2/p-2
InChIKey: JVXHQHGWBAHSSF-UHFFFAOYSA-L

Iron(II) EDTA complex Toxicity Data With Reference

1.    

ipr-mus LD50:40 mg(Fe)/kg

    PABIAQ    Pathologie et Biologie. 11 (1963),853.

Iron(II) EDTA complex Consensus Reports

Reported in EPA TSCA Inventory.

Iron(II) EDTA complex Safety Profile

Poison by intraperitoneal route. When heated to decomposition Iron(II) EDTA complex (CAS NO.21393-59-9) emits toxic fumes of NOx. See also IRON COMPOUNDS.

Iron(II) EDTA complex Specification

 Iron(II) EDTA complex , its cas register number is 21393-59-9. It also can be called Iron(II): EDTA ; Dihydrogen ((N,N'-ethylenebis(N-(carboxymethyl)glycinato))(4-)-N,N',O,O',ON,ON')ferrate(2-) ; and Ferrate(2-), ((N,N'-1,2-ethanediylbis(N-((carboxy-kappaO)methyl)glycinato-kappaN,kappaO))(4-))-, hydrogen (1:2), (OC-6-21)- .

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