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Iron(iii) arsenate (1:1)

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Name Iron(iii) arsenate (1:1) EINECS
CAS No. 10102-49-5 Density g/cm3
Solubility Melting Point
Formula AsH3 O4 . Fe Boiling Point °Cat760mmHg
Molecular Weight 194.77 Flash Point °C
Transport Information Appearance
Safety Confirmed human carcinogen. A deadly poison. A pesticide. When heated to decomposition it emits toxic fumes of As. See also ARSENIC COMPOUNDS and IRON COMPOUNDS. Risk Codes
Molecular Structure Molecular Structure of 10102-49-5 (Arsenic acid (H3AsO4),iron(3+) salt (1:1)) Hazard Symbols Toxic by ingestion and inhalation, strong irritant.
Synonyms

Ironarsenate (FeAsO4) (6CI,7CI); Ferric arsenate; Iron arsenate; Iron(III) arsenate

 

Chemistry

IUPAC Name: Iron(3+) arsorate
Synonyms of Iron(iii) arsenate (1:1) (CAS NO.10102-49-5) : Arsenate of iron, ferric ; Arsenic acid (H3AsO4), iron(3 ) salt (1:1) ; Ferric arsenate ; Iron(III) arsenate (1:1)
Product Categories: Inorganics
CAS NO:10102-49-5
Molecular Formula: AsFeO4
Molecular Weight :194.7642
Molecular Structure :
EINECS: 233-274-7
Flash Point: 325.2 °C
Enthalpy of Vaporization: 99.5 kJ/mol
Boiling Point: 614.2 °C at 760 mmHg
Vapour Pressure: 1.15E-16 mmHg at 25°C
Appearance: Iron(iii) arsenate (1:1) (CAS NO.10102-49-5) is a green or brown powder.
Water solubility: Insoluble in water

Uses

 Iron(iii) arsenate (1:1) (CAS NO.10102-49-5) is used in the manufacture of insecticides.

Consensus Reports

Arsenic and its compounds are on the Community Right-To-Know List.

Safety Profile

Confirmed human carcinogen. A deadly poison. A pesticide. When heated to decomposition it emits toxic fumes of As. See also ARSENIC COMPOUNDS and IRON COMPOUNDS.

RIDADR 1606
HazardClass 6.1(a)
PackingGroup II

Standards and Recommendations

OSHA PEL: OSHA: Cancer Hazard
ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 µ (As)/L inorganic arsenic and methylated metabolites in urine
NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/m3/15M
DOT Classification:  6.1; Label: Poison

Specification

1.General Description: Ferrous arsenate is toxic by ingestion and inhalation and is a strong irritant.
2.Reactivity Profile:Ferrous arsenate has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.
3.Health Hazard :Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
4.Fire Hazard :Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

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