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Isodrin
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Name

Isodrin

 EINECS 207-366-2
CAS No. 465-73-6 Density 1.73 g/cm3
PSA 0.00000 LogP 5.27020
Solubility N/A Melting Point 239-241 °C(lit.)
Formula C12H8 Cl6 Boiling Point 384.9 °C at 760 mmHg
Molecular Weight 364.914 Flash Point 186.1 °C
Transport Information UN 2811 6 Appearance N/A
Safety A poison by ingestion and skin contact. Causes liver injury, acne, and skin rashes. When heated to decomposition it emits toxic fumes of Cl−. See also CHLOROPHENOLS and ALDRIN. Risk Codes 26/27/28-50/53
Molecular Structure Molecular Structure of 465-73-6 (ISODRIN) Hazard Symbols Toxic, use may be restricted.
Synonyms

1,4:5,8-Dimethanonaphthalene,1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, (1a,4a,4ab,5b,8b,8ab)-; 1,4:5,8-Dimethanonaphthalene,1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, endo,endo- (8CI);1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4-endo,endo-5,8-dimethanonaphthalene;Compound 711; Isodrin; Isodrin (insecticide); SD 3418

Article Data 13

Isodrin Chemical Properties

CAS: 465-73-6
EINECS: 207-366-2
Product Categories: Alpha sort ; Alphabetic ; CyclodienesPesticides&Metabolites ; H-MAnalytical Standards ; Insecticides ; Pesticides .
Following is the Molecular Structure of Isodrin (465-73-6):

SMILES: Cl\C3=C(/Cl)[C@@]4(Cl)[C@H]2[C@H]([C@@H]1/C=C\[C@@H]2C1)[C@@]3(Cl)C4(Cl)Cl
InChI: InChI=1/C12H8Cl6/c13-8-9(14)11(16)7-5-2-1-4(3-5)6(7)10(8,15)12(11,17)18/h1-2,4-7H,3H2/t4-,5-,6-,7+,10+,11+/m1/s1
InChIKey: QBYJBZPUGVGKQQ-KCHUEWMZBO
Std.InChI: InChI=1S/C12H8Cl6/c13-8-9(14)11(16)7-5-2-1-4(3-5)6(7)10(8,15)12(11,17)18/h1-2,4-7H,3H2/t4-,5-,6-,7+,10+,11+/m1/s1
Std.InChIKey: QBYJBZPUGVGKQQ-KCHUEWMZSA-N
Molecular Formula: C12H8Cl6
Molecular Weight: 364.91
Boiling Point: 384.9℃ at 760mmHg
Flash Point: 186.1℃
Molar Volume: 210.7cm3
Density: 1.73g/cm3
Index of Refraction: 1.659
Molar Refractivity: 77.74cm3
Surface Tension: 55.3dyne/cm
Polarizability: 30.81 10-24cm3
Enthalpy of Vaporization: 60.89kJ/mol
Vapour Pressure: 8.75E-06mmHg at 25℃

Isodrin Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 unreported 7mg/kg (7mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 63, 1971.
mouse LD50 oral 8800ug/kg (8.8mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT		 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 8(4), Pg. 30, 1964.
mouse LDLo intraperitoneal 6400ug/kg (6.4mg/kg)   Toxicology and Applied Pharmacology. Vol. 23, Pg. 288, 1972.
rat LD50 oral 7mg/kg (7mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.
rat LD50 skin 23mg/kg (23mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.

Isodrin Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. Chlorophenol compounds are on the Community Right-To-Know List.

Isodrin Safety Profile

Hazard Codes:  T+ Very Toxic, T Toxic,  N Dangerous for the environment,  F Flammable.
Risk Statements: 26/27/28-50/53-39/23/24/25-23/24/25-11
R26/27/28: Very Toxic by inhalation, in contact with skin and if swallowed.
R50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R11: Highly Flammable.
Safety Statements: 13-28-45-60-61-16-7
S13: Keep away from food, drink and animal feeding stuffs.
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S60: This material and/or its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions safety data sheet.
S16: Keep away from sources of ignition-No smoking.
S7: Keep container tightly closed.
RIDADR: UN 2811 6.1/PG 2
WGK: Germany 2
RTECS: IO1925000
HazardClass: 6.1(a)
PackingGroup: II
A poison by ingestion and skin contact. Causes liver injury, acne, and skin rashes.

Isodrin Specification

 Isodrin (465-73-6),which also can be called for 1,2,3,4,10,10-Hexachloro-1,4,4A,5,8,8A-hexahydro-endo,endo-1,4:5,8-dimethanonaphthalene ; Isodrin ; Isodrine ; Isodrin emulsion(content>10%) ; Isodrin powder(content1%-10%) ; (1alpha,4alpha,4abeta,5beta,8beta,8abeta)-1,2,3,4,10,10-Hexachloro-1,4,4a,5,8, ; (1r,4s,5r,8s)-1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4:5,8-dimetha,(1alpha,4alpha,4abeta,5beta,8beta,8abeta)- .When Isodrin (465-73-6) was heated,it emits toxic fumes of Cl− . Isodrin (465-73-6) is a solid and it no longer used as a pesticide. Isodrin (465-73-6) is related to Aldrin. (nonspecific-- Aldrin ).When heated to decomposition Isodrin emits toxic fumes of Chlorine . Unstable, reactions induced by light or acid. [EPA, 1998].