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Methyl bromoacetate

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Methyl bromoacetate

EINECS 202-499-2
CAS No. 96-32-2 Density 1.615 g/cm3
PSA 26.30000 LogP 0.55430
Solubility Miscible with methanol, ether and acetone. Slightly miscible with water Melting Point -50°C
Formula C3H5BrO2 Boiling Point 154 °C at 760 mmHg
Molecular Weight 152.975 Flash Point 62.8 °C
Transport Information UN 2643 6.1/PG 2 Appearance clear to slightly yellow liquid
Safety 26-36/37/39-45-28A-36-16 Risk Codes 25-34-37-23/24/25-40-36/37/38
Molecular Structure Molecular Structure of 96-32-2 (Methyl bromoacetate) Hazard Symbols ToxicT,IrritantXi,FlammableF
Synonyms

Bromoacetic acid methyl ester;Carbomethoxymethyl bromide;Methyl 2-bromoethanoate;Methylmonobromoacetate;Methyl a-bromoacetate;NSC 2642;Aceticacid, bromo-, methyl ester (6CI,7CI,8CI,9CI);2-Bromoacetic acid methyl ester;

Article Data 31

Methyl bromoacetate Chemical Properties

Product Name: Methyl bromoacetate (CAS NO.96-32-2)

Molecular Formula: C3H5BrO2
Molecular Weight: 152.97g/mol
Mol File: 96-32-2.mol
EINECS: 202-499-2
Melting Point: -50°C
Boiling point: 154 °C at 760 mmHg
Storage Temperature: Store at R.T.
Flash Point: 62.8 °C
Density: 1.614 g/cm3
Refractive index: n20/D 1.458(lit.)
Index of Refraction: 1.449 
Molar Refractivity: 25.45 cm3 
Molar Volume: 94.7 cm3 
Surface Tension: 33.7 dyne/cm
Enthalpy of Vaporization: 39.08 kJ/mol
Vapour Pressure: 3.25 mmHg at 25°C
XLogP3-AA: 0.9
H-Bond Donor: 0
H-Bond Acceptor: 2
Structure Descriptors of Methyl bromoacetate (CAS NO.96-32-2):
  IUPAC Name: methyl 2-bromoacetate
  Canonical SMILES: COC(=O)CBr
  InChI: InChI=1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3 
  InChIKey: YDCHPLOFQATIDS-UHFFFAOYSA-N
Product Categories: Organics; C2 to C5; Carbonyl Compounds; Esters; 500 Series Drinking Water Methods; BromoEPA; Chemical Class; Halogenated; Method 552

Methyl bromoacetate Uses

 Methyl bromoacetate (CAS NO.96-32-2) is used to make vitamins and pharmaceuticals.

Methyl bromoacetate Toxicity Data With Reference

1.    

ivn-mus LDLo:16 mg/kg

    CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 6 (1954),138.

Methyl bromoacetate Consensus Reports

Reported in EPA TSCA Inventory.

Methyl bromoacetate Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of Br. See also ESTERS.
Hazard Codes  TToxic,XiIrritant,FHighly
Risk Statements  25-34-37-23/24/25-40-36/37/38 
R25 :Toxic if swallowed. 
R34:Causes burns. 
R37:Irritating to respiratory system 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R40:Limited evidence of a carcinogenic effect. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements  26-36/37/39-45-28A-36-16 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36:Wear suitable protective clothing. 
S16:Keep away from sources of ignition.
RIDADR  UN 2643 6.1/PG 2
WGK Germany  3
RTECS  AF6300000
F  19
HazardClass  6.1
PackingGroup  II
HS Code  29159080

Methyl bromoacetate Standards and Recommendations

DOT Classification:  6.1; Label: Poison

Methyl bromoacetate Specification

 Methyl bromoacetate , its CAS NO. is 96-32-2, the synonyms are Methyl alpha-bromoacetate ; Methyl monobromoacetate ; Methylester kyseliny bromoctove ; Acetic acid, 2-bromo-, methyl ester ; Acetic acid, bromo-, methyl ester .

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