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| Name |
Metiram |
EINECS | 157oC (decomposes) |
| CAS No. | 9006-42-2 | Density | g/cm3 |
| PSA | 102.32000 | LogP | 0.64930 |
| Solubility | N/A | Melting Point |
156 oC |
| Formula | C4H6N2S4Zn | Boiling Point | 308.2°Cat760mmHg |
| Molecular Weight | 818.69388 | Flash Point | 140.2°C |
| Transport Information | UN 1282 3 / PGII | Appearance | Off-White Solid |
| Safety | Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx, NOx, ZnO, and NH3. See also ETHYLENE BIS(DITHIOCARBAMATO)ZINC, CARBAMATES, SULFIDES, and ZINC COMPOUNDS. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Polyram(8CI);Amarex;Carbatene;Metiram-zinc;NIA 9102;Phytox-Super;Polycarbacin;Polycarbacine;Polycarbazin;Polycarbazine;Polykarbacin;Polymarcin;Polymarcine;Polymarsin;Polymarzin;Polymarzine;Polymat;Polyram 2000;Polyram 80;Polyram 80WP;Polyram DF;Polyram combi; |
Metiram Chemical Properties
IUPAC Name: Zinc N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
Synonyms: Carbamodithioic acid, 1,2-ethanediylbis-, zinc salt (1:1) ; Carbamodithioic acid, N,N'-1,2-ethanediylbis-, zinc salt (1:1) ; Metiram-zinc ; Zinc 1,2-ethanediyldicarbamodithioate ; Zinc ethane-1,2-diylbis(dithiocarbamate) ; Zinc ethane-1,2-diyldicarbamodithioate ; Zink-1,2-ethandiylbis(dithiocarbamat)
Empirical Formula of Metiram (CAS NO.9006-42-2) : C4H6N2S4Zn
Molecular Weight of Metiram (CAS NO.9006-42-2) : 275.7728
Molecular Structure of Metiram (CAS NO.9006-42-2) :.png)
CAS NO: 9006-42-2
Flash Point: 140.2 °C
Enthalpy of Vaporization: 54.88 kJ/mol
Boiling Point: 308.2 °C at 760 mmHg
Vapour Pressure: 0.000692 mmHg at 25°C
Metiram Uses
Metriram is a polymeric dithiocarbamic fungicide used in agriculture. Metiram is present as a mixture rather than a complex and is not assigned an ISO name. Metiram is used commonly in the protection of grapevines, apples, tomatoes, potatoes as well as other crops.
Metiram Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| chicken | LD50 | oral | 7660mg/kg (7660mg/kg) | Veterinariya. Veterinary Science. Vol. 56(6), Pg. 59, 1980. | |
| domestic animals - goat/sheep | LD50 | oral | 1gm/kg (1000mg/kg) | Veterinariya. Veterinary Science. Vol. 56(6), Pg. 59, 1980. | |
| guinea pig | LD50 | oral | 2400mg/kg (2400mg/kg) | Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 923, 1966. | |
| guinea pig | LD50 | unreported | 3750mg/kg (3750mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(2), Pg. 33, 1988. | |
| mammal (species unspecified) | LC50 | inhalation | 5250mg/m3 (5250mg/m3) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(12), Pg. 8, 1990. | |
| mammal (species unspecified) | LD50 | unreported | 3290mg/kg (3290mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(5), Pg. 29, 1980. | |
| mouse | LD50 | oral | 2630mg/kg (2630mg/kg) | Veterinariya. Veterinary Science. Vol. 56(6), Pg. 59, 1980. | |
| rabbit | LD50 | oral | 620mg/kg (620mg/kg) | Veterinariya. Veterinary Science. Vol. 56(6), Pg. 59, 1980. | |
| rat | LC50 | inhalation | > 5700mg/m3/4H (5700mg/m3) | Pesticide Manual. Vol. 9, Pg. 864, 1991. | |
| rat | LD50 | oral | 2850mg/kg (2850mg/kg) | Vrachebnoe Delo. Medical Practice. Vol. (9), Pg. 130, 1975. | |
| rat | LD50 | skin | > 2gm/kg (2000mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C202, 1991. | |
| rat | LD50 | unreported | 3250mg/kg (3250mg/kg) | Environmental Quality and Safety, Supplement. Vol. 3, Pg. 618, 1975. |
Metiram Consensus Reports
Zinc and its compounds are on the Community Right-To-Know List. EPA Genetic Toxicology Program.
Metiram Safety Profile
Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx, NOx, ZnO, and NH3. See also ETHYLENE BIS(DITHIOCARBAMATO)ZINC, CARBAMATES, SULFIDES, and ZINC COMPOUNDS.
Metiram Specification
Physical Properties
| Physical Property | Value | Units | Temp (deg C) | Source |
|---|---|---|---|---|
| Melting Point | 140 dec | deg C | EXP | |
| log P (octanol-water) | 0.3 | (none) | EXP | |
| Water Solubility | 1.45E+04 | mg/L | 25 | EST |
| Vapor Pressure | 7.50E-08 | mm Hg | 25 | EST |
| Henry's Law Constant | 5.33E-08 | atm-m3/mole | 25 | EST |
| Atmospheric OH Rate Constant | 3.60E-10 | cm3/molecule-sec | 25 | EST |
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