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N-(DICHLOROFLUOROMETHYLTHIO)-N
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Name

N-(DICHLOROFLUOROMETHYLTHIO)-N

 EINECS 214-118-7
CAS No. 1085-98-9 Density 1.553 g/cm3
PSA 74.30000 LogP 4.08680
Solubility 1.3mgl-1 Melting Point 105.6℃
Formula C9H11 Cl2 F N2 O2 S2 Boiling Point 336.8 ºC at 760 mmHg
Molecular Weight 333.235 Flash Point 157.5ºC
Transport Information N/A Appearance N/A
Safety 24-37-60-61-36-26-16 Risk Codes 20-36-43-50/53-20/21/22-11
Molecular Structure Molecular Structure of 1085-98-9 (DICHLOFLUANID) Hazard Symbols HarmfulXnDangerousNFlammableF
Synonyms

Sulfamide,N-[(dichlorofluoromethyl)thio]-N',N'-dimethyl-N-phenyl- (7CI,8CI);BAY 47531;Bayer 47531;Chlormethionate;Coatcide TW;Dichlofluanid;Dichlofluanide;Diclofluanide;Elvaron;Eparen;Euparen;Euparen WG;Lichenicide 246;N,N-Dimethyl-N'-(dichlorofluoromethylthio)-N'-phenylsulfamide;N,N-Dimethyl-N'-phenyl-N'-(dichlorofluoromethylthio)sulfamide;N,N-Dimethyl-N'-phenyl-N'-(fluorodichloromethylthio)sulfamide;N-Phenyl-N-(fluorodichloromethylsulfenyl)-N',N'-dimethylsulfamide;N-[(Dichlorofluoromethyl)thio]-N',N'-dimethyl-N-phenylsulfamide;NSC 218451;N'-(Dichlorofluoromethylthio)-N,N-dimethyl-N'-phenylsulfamide;Oiparen;Pecudin;Preventol A 4;Preventol A 4S;

Article Data 10

N-(DICHLOROFLUOROMETHYLTHIO)-N Synthetic route

4710-17-2

N,N-dimethyl-N'-phenylsulfonamide

2712-93-8

dichlorofluoromethanesulphenyl chloride

1085-98-9

N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide

Conditions
ConditionsYield
Stage #1: N,N-dimethyl-N'-phenylsulfonamide With sodium hydride In toluene at 0 - 20℃; for 1h;
Stage #2: dichlorofluoromethanesulphenyl chloride In toluene at 20℃;		84.2%
4710-17-2

N,N-dimethyl-N'-phenylsulfonamide

121-44-8

triethylamine

2712-93-8

dichlorofluoromethanesulphenyl chloride

1085-98-9

N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide

1085-98-9

N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide

675-63-8

bis(dichlorofluoromethyl)disulfane

Conditions
ConditionsYield
In acetone Irradiation (UV/VIS); together with other products;
In acetone Irradiation (UV/VIS); together with other products;

N-(DICHLOROFLUOROMETHYLTHIO)-N Chemical Properties

MF: C9H11Cl2FN2O2S2
The structure N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9):
                                      
MW: 333.23
EINECS: 214-118-7
 Molar Volume: 214.4 cm3       dyne/cm  Density: 1.553 g/cm3     
Polarizability: 29.74 10-24cm3   Surface Tension: 57.3             
Flash Point: 157.5 °C          Boiling Point: 336.8 °C at 760 mmHg    
Enthalpy of Vaporization: 58 kJ/mol  
Vapour Pressure: 0.00011 mmHg at 25°C
Synonyms of N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9):  DICHLOFLUANID,N'-DIMETHYL-N-PHENYLSULFAMIDE;ELVARON ;  N-[(DICHLOROFLUOROMETHYL)THIO]-N',N'-DIMETHYL-N-PHENYLSULPHAMIDE;DICHLOFLUANID;Dichlofluanid emulsion(content>25%);EUPAREN(R);EUPAREN;1,1-dichloro-n-((dimethylamino)sulfonyl)-1-fluoro-n-phenyl-methanesulfenamid
Product Categories  of N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9): Organics;AcaricidesPesticides;Alpha sort;Amide
structurePesticides&Metabolites;D;DAlphabetic;DIA -DIC;Fungicides;Pesticides;Pesticides&Metabolites;Amide structureAlphabetic

N-(DICHLOROFLUOROMETHYLTHIO)-N Uses

N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9) could be used as Protective fungicides.
N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9) also could be used as a  bactericide of broad spectrum .
N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9) can be mainly used for prevention and control of  fungal diseases of citrus, grapes and other fruits and vegetables.

N-(DICHLOROFLUOROMETHYLTHIO)-N Production

N-(DICHLOROFLUOROMETHYLTHIO)-N (1085-98-9) is prepared with aniline as raw material.

N-(DICHLOROFLUOROMETHYLTHIO)-N Toxicity Data With Reference

1.   

mmo-esc 10 µg/plate

   MUREAV    Mutation Research. 116 (1983),185.
2.   

mma-esc 100 µg/plate

   MUREAV    Mutation Research. 116 (1983),185.
3.   

orl-rat LD50:500 mg/kg

   WRPCA2    World Review of Pest Control. 9 (1970),119.
4.   

ihl-rat LC50:300 mg/m3/4H

   85JFAN    “Agrochemicals Handbook“, with updates, Hartley, D., and H. Kidd, eds., Nottingham, UK, Royal Soc. of Chemistry, 1983-86 A136 ,1986.
5.   

skn-rat LD50:1 g/kg

   GUCHAZ    Guide to the Chemicals Used in Crop Protection 6 (1973),179.
6.   

orl-mus LD50:1250 mg/kg

   MEIEDD    Merck Index. 10 (1983),442.
7.   

orl-cat LD50:1 g/kg

   85GYAZ    Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen 2nd ed.,Klimmer, O.R.,Hattingen, Germany.: Hundt-Verlag,1971,97.

N-(DICHLOROFLUOROMETHYLTHIO)-N Consensus Reports

EPA Genetic Toxicology Program.

N-(DICHLOROFLUOROMETHYLTHIO)-N Safety Profile

Moderately toxic by ingestion and skin contact. Mutation data reported. A pesticide. When heated to decomposition it emits very toxic fumes of Cl−, F−, NOx, and SOx.
Hazard Codes  Xn,N,F
Risk Statements
11:Highly Flammable
20:Harmful by inhalation
21:Harmful in contact with skin
22:Harmful if swallowed
36:Irritating to the eyes  
43:May cause sensitization by skin contact 
50:Very Toxic to aquatic organisms
53:May cause long-term adverse effects in the aquatic environment
Safety Statements
16:Keep away from sources of ignition - No smoking
24:Avoid contact with skin
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:Wear suitable protective clothing
37:Wear suitable gloves
60:This material and/or its container must be disposed of as hazardous waste
61:Avoid release to the environment. Refer to special instructions safety data sheet

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