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N-Isopropylhydroxylamine
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  • Name N-Isopropylhydroxylamine
  • EINECS225-791-1
  • CAS No. 5080-22-8
  • Density0.886 g/cm3
  • PSA32.26000
  • LogP0.76450
  • Solubility199g/L at 25℃
  • Melting Point159-160 °C (dec.)
  • FormulaC3H9NO
  • Boiling Point104.9 °C at 760 mmHg
  • Molecular Weight75.1106
  • Flash Point44.5 °C
  • Transport InformationN/A
  • AppearanceN/A
  • Safety24/25
  • Risk Codes21/22
  • Molecular Structure
    Molecular Structure of 5080-22-8 (N-Isopropylhydroxylamine)
  • Hazard SymbolsHarmfulXn
  • SynonymsHarmfulXn
  • Article Data29

N-Isopropylhydroxylamine Synthetic route

113768-49-3

2-Isopropyl-3-methyl-5-oxo-2,5-dihydro-isoxazole-4-carboxylic acid ethyl ester

5080-22-8

N-isopropylhydroxyamine

Conditions
ConditionsYield
With hydrogenchloride; acetic acid In water96%
79-46-9

2-nitropropane

A

75-31-0

isopropylamine

B

5080-22-8

N-isopropylhydroxyamine

Conditions
ConditionsYield
With hydrogen In para-xylene; isopropyl alcohol at 25℃; under 760.051 Torr; for 4h;A 9%
B 88%
79-46-9

2-nitropropane

5080-22-8

N-isopropylhydroxyamine

Conditions
ConditionsYield
With ammonia borane; gold on titanium oxide In ethanol at 20℃; for 0.666667h; Inert atmosphere;85%
elektrochemische Reduktion;
With ammonia; sodium at -33.5℃;
7647-01-0

hydrogenchloride

3-nitro-benzaldehyde-(N-isopropyl oxime )

A

99-61-6

3-nitro-benzaldehyde

B

5080-22-8

N-isopropylhydroxyamine

m-nitro-N-isopropyl-isobenzaldoxime

m-nitro-N-isopropyl-isobenzaldoxime

A

99-61-6

3-nitro-benzaldehyde

B

5080-22-8

N-isopropylhydroxyamine

Conditions
ConditionsYield
With hydrogenchloride
79-46-9

2-nitropropane

7664-41-7

ammonia

sodium

sodium

5080-22-8

N-isopropylhydroxyamine

7647-01-0

hydrogenchloride

127-06-0

acetone oxime

platinum black

platinum black

A

5765-61-7

N,N-diisopropylhydroxylamine

B

5080-22-8

N-isopropylhydroxyamine

C

N-isopropyl-hydroxylammonium chloride

N-isopropyl-hydroxylammonium chloride

D

N.N-diisopropyl-hydroxylammonium chloride

N.N-diisopropyl-hydroxylammonium chloride

Conditions
ConditionsYield
Hydrogenation;
...Expand
144-62-7

oxalic acid

127-06-0

acetone oxime

platinum black

platinum black

A

5765-61-7

N,N-diisopropylhydroxylamine

B

5080-22-8

N-isopropylhydroxyamine

C

N-isopropyl-hydroxylammonium oxalate

N-isopropyl-hydroxylammonium oxalate

D

N.N-diisopropyl-hydroxylammonium oxalate

N.N-diisopropyl-hydroxylammonium oxalate

Conditions
ConditionsYield
Hydrogenation;
...Expand
127-06-0

acetone oxime

5080-22-8

N-isopropylhydroxyamine

Conditions
ConditionsYield
Inert atmosphere;
Stage #1: acetone oxime With sodium cyanoborohydride In methanol at 20℃; for 4h;
Stage #2: With hydrogenchloride In methanol
123-38-6

propionaldehyde

5080-22-8

N-isopropylhydroxyamine

107341-57-1, 118644-19-2, 118644-29-4

C6H13NO

Conditions
ConditionsYield
In ethanol at 20℃; for 0.5h;100%

N-Isopropylhydroxylamine Chemical Properties

The molecular structure of 2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) is

IUPAC Name: N-Propan-2-ylhydroxylamine  
Canonical SMILES: CC(C)NO
Molecular Formula: C3H9 N O
Molecular Weight: 75.11
EINECS: 225-791-1
Density: 0.886g/cm3
Melting Point: 159-160 °C (dec.)
Boiling Point: 104.9°C at 760mmHg
Flash Point: 44.5°C 
Freely Rotating Bonds: 2
Polar Surface Area: 12.47 Å2
Index of Refraction: 1.41
Molar Refractivity: 21.03 cm3
Molar Volume: 84.7 cm3
Polarizability: 8.33× 10-24 cm3
Surface Tension: 27.2 dyne/cm
Enthalpy of Vaporization: 40.09 kJ/mol
Vapour Pressure: 16.5 mmHg at 25°C
The Cas Register Number  of 2-Propanamine,N-hydroxy- is 5080-22-8. The chemical synonyms of 2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) are N-hydroxy-2-propanamin ; N-hydroxy-2-Propaneamine ; N-isopropylhydroxylamineoxalate ; IPHA ; N-Isopropylhydroxylamine ; N-Isopropylhydroxylamine oxalate salt ; 2-Propanamine, N-hydroxy- ; 2-hydroxylaminopropane .

N-Isopropylhydroxylamine Uses

  2-Propanamine,N-hydroxy- (CAS NO.5080-22-8) is used in organic synthesis.

N-Isopropylhydroxylamine Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 21/22 
R21/22: Harmful in contact with skin and if swallowed.
Safety Statements: 24/25 
S24/25: Avoid contact with skin and eyes.

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