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Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1)

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Name

Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1)

EINECS 219-159-4
CAS No. 2378-86-1 Density N/A
PSA 13.59000 LogP 2.49310
Solubility N/A Melting Point 268-270°C
Formula C26H24BrP Boiling Point N/A
Molecular Weight 447.354 Flash Point N/A
Transport Information N/A Appearance N/A
Safety 26-36/37/39 Risk Codes 22-36/37/38
Molecular Structure Molecular Structure of 2378-86-1 ((4-METHYLBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE) Hazard Symbols R22:Harmful if swallowed.; R36/37/38:Irritating to eyes, respiratory system and skin.;
Synonyms

(p-Methylbenzyl)triphenylphosphoniumbromide (6CI,7CI);Phosphonium, (p-methylbenzyl)triphenyl-, bromide (8CI);Phosphonium, [(4-methylphenyl)methyl]triphenyl-, bromide (9CI);4-Methylbenzyltriphenylphosphonium bromide;NSC 77141;

Article Data 36

Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1) Specification

The Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1) is an organic compound with the formula C26H24BrP. The IUPAC name of this chemical is (4-methylphenyl)methyl-triphenylphosphanium bromide. With the CAS registry number 2378-86-1, it is also named as [(4-methylphenyl)methyl]triphenylphosphine, bromide. The product's category is Ligand.

Preparation of Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1): this chemical can be prepared by 1-bromomethyl-4-methyl-benzene and triphenylphosphane. This reaction is a kind of Substitution. This reaction will need solvent benzene. The reaction time is 12 hours by heating.

Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1) can be prepared by 1-bromomethyl-4-methyl-benzene and triphenylphosphane

Uses of Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1): it can be used to produce [α-(Dichlorphosphanyl)-4-methylbenzyliden]triphenylphosphoran at ambient temperature. It will need reagents triethylamine, PCl3 and solvent CH2Cl2 with reaction time of 15 hours. The yield is about 76%.

Phosphonium,[(4-methylphenyl)methyl]triphenyl-, bromide (1:1) can be used to produce [α-(Dichlorphosphanyl)-4-methylbenzyliden]triphenylphosphoran

When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)SMILES: [Br-].c1(ccc(cc1)C)C[P+](c2ccccc2)(c3ccccc3)c4ccccc4
(2)InChI: InChI=1/C26H24P.BrH/c1-22-17-19-23(20-18-22)21-27(24-11-5-2-6-12-24,25-13-7-3-8-14-25)26-15-9-4-10-16-26;/h2-20H,21H2,1H3;1H/q+1;/p-1
(3)InChIKey: CEEKCHGNKYVTTM-REWHXWOFAQ
(4)Std. InChI: InChI=1S/C26H24P.BrH/c1-22-17-19-23(20-18-22)21-27(24-11-5-2-6-12-24,25-13-7-3-8-14-25)26-15-9-4-10-16-26;/h2-20H,21H2,1H3;1H/q+1;/p-1
(5)Std. InChIKey: CEEKCHGNKYVTTM-UHFFFAOYSA-M

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