Welcome to LookChem.com Sign In | Join Free Post buying lead Chemical Tools
Home > Hot Product_List > Potassium permanganate

Basic information

  • Name:
  • Potassium permanganate

  • CAS No.:
  • 7722-64-7

  • Molecular Structure:
  • Formula:
  • KMnO4
  • Molecular Weight:
  • 158.04
  • Deleted CAS:
  • 146104-97-4
  • Synonyms:
  • Permanganicacid (HMnO4), potassium salt (8CI,9CI);Allways Fresh;C.I. 77755;Cairox;Chameleon mineral;Condy's crystals;GS-KP;HY 5;Permanganic acid potassiumsalt;Pure Light E 2;Tarco 4338C;Turco 4338C;
  • EINECS:
  • 231-760-3
  • Density:
  • 1.01 g/mL at 25 °C
  • Melting Point:
  • 240 °C
  • Solubility:
  • water: 6.4 g/100 mL (20 °C)
  • Appearance:
  • purplish colored crystalline solid
  • Hazard Symbols:
  • OxidizingO,HarmfulXn,DangerousN,IrritantXi
  • Risk Codes:
  • 8-51/53-50/53-22-52/53-36/38
  • Safety Description:
  • 60-61-36-26 Details
  • Transport Information:
  • UN 3082 9/PG 3

Famous Chemical Enterprises

  • Livzon
  • Total
  • Shell
  • Dupont
  • Exxonmobil
  • Akzonobel
  • Basf
  • Bayer
  • BP

Please post your buying leads,so that our qualified suppliers will soon contact you!
*Required Fields

Chemistry

Molecular structure of Potassium permanganate (CAS NO.7722-64-7) is:

Product Name: Potassium permanganate
CAS Registry Number: 7722-64-7
IUPAC Name: potassium permanganate
Molecular Weight: 158.033949 [g/mol]
Molecular Formula: KMnO4
H-Bond Donor: 0
H-Bond Acceptor: 4 
EINECS: 231-760-3
Melting Point: 240 °C
Density: 1.01 g/mL at 25 °C
Storage temp.: Store at RT.
Solubility: H2O: 0.1 M at 20 °C, complete, violet
Form: solution (volumetric)
Water Solubility: 6.4 g/100 mL (20 °C)
Stability: Stable, but contact with combustible material may cause fire. Substances to be avoided include reducing agents, strong acids, organic material, combustible materials, peroxides, alcohols and chemically active metals. Strong oxidant.
Product Categories: INORGANIC & ORGANIC CHEMICALS;Inorganic Chemicals;Analytical Chemistry;TLC Stains;OthersEssential Chemicals;Oxidation;Reagent Grade;Routine Reagents;Synthetic Reagents;Concentrates (e.g. FIXANAL);Salt Concentrates;Titration;Decomposition ReagentsAnalytical/Chromatography;Analytical Reagents;Special Applications;Trace Analysis Reagents;N - RSynthetic Reagents;Others;Salt Solutions;Volumetric Solutions;Microscopy Reagents and Kits;Staining Solutions;Staining Solutions for MycobacteriaAnalytical Reagents;Microscopy Reagents;Stains and Dyes;OthersPharmacopoeia (USP);Pharmacopoeia A-ZPharmacopoeia (USP);Pharmacopoeial Inorganics;ACS GradeSynthetic Reagents;Essential Chemicals;Analytical Reagents for General Use;O-P, Puriss p.a. ACS;Puriss p.a. ACS

History

In 1659 a German chemist, J.R. Glauber, fused a mixture of the mineral pyrolusite and potassium carbonate to obtain a material that, when dissolved in water, gave a green solution (potassium manganate) which slowly shifted to violet potassium permanganate and then finally red. This report represents the first description of the production of potassium permanganate. Just under two hundred years later London chemist Henry Bollmann Condy had an interest in disinfectants, and marketed several products including ozonised water. He found that fusing pyrolusite with NaOH and dissolving it in water produced a solution with disinfectant properties. He patented this solution, and marketed it as Condy's Fluid. Although effective, the solution was not very stable. This was overcome by using KOH rather than NaOH. This was more stable, and had the advantage of easy conversion to the equally effective potassium permanganate crystals. This crystalline material was known as Condy’s crystals or Condy’s powder. Potassium permanganate was comparatively easy to manufacture so Condy was subsequently forced to spend considerable time in litigation in order to stop competitors from marketing products similar to Condy's Fluid or Condy's Crystals.

Uses

Almost all applications of Potassium permanganate (CAS NO.7722-64-7) exploit its oxidizing properties.As a strong oxidant that does not generate toxic byproducts, it has many niche uses.Following is the uses: Disinfectant and water treatment,As an oxidant, potassium permanganate can act as a disinfectant; Biomedical uses,Related to the use of KMnO4 for water treatment, this salt is often employed as a specialized disinfectant for treating human and animal ailments; Organic synthesis,Aside from its use in water treatment, the other major application of KMnO4 is as a reagent for the synthesis of organic compounds; Analytical chemistry, Potassium permanganate can be used to quantitatively determine the total oxidisable organic material in an aqueous sample; Organic chemistry, Dilute solutions of KMnO4 convert alkenes into diols (glycols).

Production

 Potassium permanganate (CAS NO.7722-64-7) is manufactured on a large scale from manganese dioxide. The mineral pyrolusite is fused with potassium hydroxide and heated in air or with potassium nitrate. This process gives potassium manganate, which upon electrolytic oxidation in alkaline solution gives potassium permanganate.
2 MnO2 + 2 KOH + 3/2 O2 → 2 KMnO4 + H2O
2MnO42- + Cl2 → 2MnO4-+ 2Cl-

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo oral 400mg/kg (400mg/kg)   Yakkyoku. Pharmacy. Vol. 31, Pg. 855, 1980.
guinea pig LD50 oral 1151mg/kg (1151mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 36(9), Pg. 15, 1971.
human LDLo oral 143mg/kg (143mg/kg) LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: OTHER CHANGES
"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 493, 1969.
mouse LD50 oral 2157mg/kg (2157mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 36(9), Pg. 15, 1971.
rabbit LDLo intravenous 70mg/kg (70mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo oral 600mg/kg (600mg/kg)   Yakkyoku. Pharmacy. Vol. 31, Pg. 855, 1980.
rat LD50 oral 1090mg/kg (1090mg/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
women LDLo oral 100mg/kg (100mg/kg) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), DIFFUSE"

KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"
Human & Experimental Toxicology. Vol. 15, Pg. 259, 1996.
women TDLo oral 2400ug/kg/D (2.4mg/kg) GASTROINTESTINAL: NAUSEA OR VOMITING Archives Internationales de Pharmacodynamie et de Therapie. Vol. 44, Pg. 446, 1933.

Safety Profile

R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Codes: OxidizingO; HarmfulXn,Xi; DangerousN
Risk Statements: 8-51/53-50/53-22-52/53-36/38 
R8 :Contact with combustible material may cause fire. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R22:Harmful if swallowed. 
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R36/38:Irritating to eyes and skin.
Safety Statements: 60-61-36-26 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S36:Wear suitable protective clothing. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 3082 9/PG 3
WGK Germany: 3
RTECS: SD6475000
HazardClass: 5.1
PackingGroup: II

Specification

 Potassium permanganate , its cas register number is 7722-64-7. It also can be called Algae-K ; Argucide ; Cairox ; Condy's crystals ; Diversey Diversol CX with Arodyne ; Icc 237 Disinfectant, Sanitizer, Destainer, and Deodorizer ; Insta-perm ; Kaliumpermanganat ; Permanganate de potassium ; Permanganate of potash .It is a purplish colored crystalline solid. Noncombustible but accelerates the burning of combustible material. If the combustible material is finely divided the mixture may be explosive. It contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fire or explosion. Soluble in water.

Please post your buying leads
so that our qualified suppliers will soon contact you!

©2008 LookChem.com,License:ICP NO.:Zhejiang10014259

[Hangzhou]86-571-85317600,85317603,85317620