Phenyl(10-phenylanthracen-9-yl)methanone

Base Information

• Chemical Name: Phenyl(10-phenylanthracen-9-yl)methanone
• CAS No.: 24451-63-6
• Molecular Formula: C27H18 O
• Molecular Weight: 358.439
• NSC Number: 157853
• DSSTox Substance ID: DTXSID40303325
• Nikkaji Number: J2.393.312H
• Wikidata: Q82048528
• Mol file: 24451-63-6.mol

Synonyms:24451-63-6;phenyl(10-phenylanthracen-9-yl)methanone;NSC157853;DTXSID40303325;NSC-157853

Chemical Property of Phenyl(10-phenylanthracen-9-yl)methanone

Chemical Property:

• Vapor Pressure: 1.16E-11mmHg at 25°C
• Boiling Point: 538.4°C at 760 mmHg
• Flash Point: 235.4°C
• Density: 1.19g/cm³
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 358.135765193
• Heavy Atom Count: 28
• Complexity: 502

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC=CC3=C(C4=CC=CC=C42)C(=O)C5=CC=CC=C5

Technology Process of Phenyl(10-phenylanthracen-9-yl)methanone

There total 9 articles about Phenyl(10-phenylanthracen-9-yl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) + (phenyl)[2-(2-phenylethynyl)phenyl]methanone (221458-86-2) → (phenyl)(9-phenylanthracen-10-yl)methanone (24451-63-6)

Guidance literature:

anthranilic acid; With isopentyl nitrite; trichloroacetic acid; In tetrahydrofuran; at 20 ℃; for 1h;

(phenyl)[2-(2-phenylethynyl)phenyl]methanone; With gold(I) chloride; In 1,2-dichloro-ethane; at 40 ℃; for 8h;

DOI:10.1021/ol062268m

Reference yield: 72.0%

benzenedizolium-2-carboxylate (1608-42-0) + (phenyl)[2-(2-phenylethynyl)phenyl]methanone (221458-86-2) → (phenyl)(9-phenylanthracen-10-yl)methanone (24451-63-6)

Guidance literature:

With gold(I) chloride; In 1,2-dichloro-ethane; at 40 ℃; for 8h;

DOI:10.1016/j.tet.2007.10.083

Reference yield: 62.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) + 1,3-diphenylisobenzopyrylium trifluoromethanesulfonate → (phenyl)(9-phenylanthracen-10-yl)methanone (24451-63-6)

Guidance literature:

anthranilic acid; With isopentyl nitrite; trichloroacetic acid; In tetrahydrofuran; at 20 ℃; for 1h;

1,3-diphenylisobenzopyrylium trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 80 ℃; for 3h;

DOI:10.1021/ol062268m

upstream raw materials:

9-phenylanthracene

benzoic acid anhydride

benzoyl chloride

carbon disulfide

Downstream raw materials:

9-phenylanthracene

(10-phenylanthracen-9-yl)benzyl alcohol

9-benzyl-10-phenyl-anthracene

benzoic acid

Refernces

• 1、 Naoki, Asao,Sato, Kenichiro. "AuCl-catalyzed [4+2] benzannulation between o-alkynyl(oxo)benzene and benzyne". . p. 5361 - 5363. Retrieved 2006.