Tricyclohexylstannanylium;chloride

Base Information

• Chemical Name: Tricyclohexylstannanylium;chloride
• CAS No.: 3091-32-5
• Molecular Formula: C18H33ClSn
• Molecular Weight: 403.623
• Hs Code.: 29319090
• Mol file: 3091-32-5.mol

Synonyms:tricyclohexylstannanylium;chloride;SCHEMBL1031813

Chemical Property of Tricyclohexylstannanylium;chloride

Chemical Property:

• Vapor Pressure: 1.61E-06mmHg at 25°C
• Melting Point: 123-125 °C(lit.)
• Boiling Point: 408.8 °C at 760 mmHg
• Flash Point: 201.1 °C
• PSA: 0.00000
• LogP: 7.17360
• Storage Temp.: 2-8°C
• Water Solubility.: Soluble in ethanol, ether, toluene and chloroform. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 404.129281
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tricyclohexylchlorotin ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn,N
• Statements: 20/21/22-50/53
• Safety Statements: 26-28-61-60

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(CC1)[Sn+](C2CCCCC2)C3CCCCC3.[Cl-]
• Uses: Tricyclohexyltin chloride is used in the preparation of dicyclohexyl disulfide. It is also used in the synthesis of organotin derivatives of 2-thiophene carboxylic acid as enzyme inhibitors and antibacterial agents.

Technology Process of Tricyclohexylstannanylium;chloride

There total 18 articles about Tricyclohexylstannanylium;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tris(cyclohexyl)(phenyl)stannane (20204-08-4) + tin(IV) chloride (7646-78-8) → tricyclohexyltin(IV) chloride (3091-32-5)

Guidance literature:

In xylene; refluxing, 0.5h;;

Reference yield: 82.0%

→ tricyclohexyltin(IV) chloride (3091-32-5)

Guidance literature:

Reference yield: 80.0%

tin(IV) chloride (7646-78-8) + dichlorohexylaluminum chloride (2444-78-2) → tricyclohexyltin(IV) chloride (3091-32-5)

Guidance literature:

With hydrogenchloride; In dibutyl ether; xylene; Ar atmosphere; addn. Bu2O, and SnCl4 in xylene to Cy2AlCl, heating (80-85°C, 3 h), cooling, addn. of aq. HCl; drying of org. layer (over CaCl2), distn., addn. of PrOH, refluxing (0.5 h), filtration, evapn. (vac.), solidifing (-78°C, hexane), recrystn. (hexane); elem. anal.;

DOI:10.1007/BF01141731

upstream raw materials:

(cyclo-C₆H₁₁)3SnC₄H₉

Trichlorbutylstannan

Iodine monochloride

Tetracyclohexyl-stannan

Downstream raw materials:

2-(2'-Furyl)-4-Tricyclohexylstannyl-5-Oxo-1,3,4-Oxadiazoline

4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide

4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfone

tetraphenyltin(IV)

Refernces

• 1、 -. "Recycling of organotin compounds". Paragraph 0076. . Retrieved 2013/12/02.
• 2、 Dumartin, Marie-Laurence,El Hamzaoui, Hicham,Jousseaume, Bernard,Rascle, Marie-Claude,Toupance, Thierry,Allouchi, Hassan. "Synthesis and characterization of lipophilic organotins. Application to the functionalization of silica gel". . p. 5576 - 5580. Retrieved 2008/10/09.