(5E,7Z)-5,7-Dodecadien-1-ol

Base Information

• Chemical Name: (5E,7Z)-5,7-Dodecadien-1-ol
• CAS No.: 72922-18-0
• Molecular Formula: C₁₂H₂₂O
• Molecular Weight: 182.306
• Mol file: 72922-18-0.mol

Synonyms:(5E,7Z)-dodecadien-1-ol;dodeca-5E,7Z-dien-1-ol;5E,7Z-dodecadien-1-ol;(E,Z)-5,7-Dodecadien-1-ol;(5E,7E)-5,7-dodecadien-1-ol;(5E,7Z)-Dodeca-5,7-dien-1-ol;(5E,7Z)-5,7-Dodecadien-1-ol;

Chemical Property of (5E,7Z)-5,7-Dodecadien-1-ol

Chemical Property:

• PSA: 20.23000
• LogP: 3.45160

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (5E,7Z)-5,7-Dodecadien-1-ol

There total 29 articles about (5E,7Z)-5,7-Dodecadien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.3%

(5E,7Z)-tetrahydro-2-<(5,7-dodecadienyl)oxy>-2H-pyran (82750-98-9,82751-04-0,96754-50-6,107148-53-8) → (5E,7Z)-5,7-dodecadien-1-ol (72922-18-0,71510-51-5)

Guidance literature:

With pyridinium p-toluenesulfonate; In ethanol; at 55 ℃; for 3h;

DOI:10.1021/ja00241a035

Reference yield: 89.0%

(5E,7Z)-dodeca-5,7-dienal (75539-65-0) → (5E,7Z)-5,7-dodecadien-1-ol (72922-18-0,71510-51-5)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 1h;

Reference yield: 60.0%

(5E,7Z)-1,5,7-Dodecatrien (83085-83-0) → (5E,7Z)-5,7-dodecadien-1-ol (72922-18-0,71510-51-5)

Guidance literature:

(5E,7Z)-1,5,7-Dodecatrien; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; for 2h;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; water; at 25 ℃; for 2h;

DOI:10.1007/BF02234863

upstream raw materials:

pentyltriphenylphosphonium bromide

(E)-7-<(tetrahydro-2H-pyran-2-yl)oxy>-2-heptenal

(5E,7Z)-1,5,7-Dodecatrien

(5E,7Z)-dodeca-5,7-dienal

Downstream raw materials:

(5E,7Z)-5,7-dodecadienyl acetate

(5E,7Z)-dodeca-5,7-dienal

Refernces

• 1、 Kukovinets,Kasradze,Salimova,Odinokov,Galin,Fedorov. "Insect pheromones and their analogs LIX. A new method for the synthesis of components of the sex pheromones of insects of the genus Malacosoma". . p. 358 - 360. Retrieved 2007/10/03.
• 2、 Huang,Shi,Yang,Cai. "Highly stereoselective synthesis of Z,E conjugated diene type sex pheromones". . p. 3558 - 3560. Retrieved 2007/10/02.