2,4-DIHYDROXYACETOPHENONE OXIME

Base Information

• Chemical Name: 2,4-DIHYDROXYACETOPHENONE OXIME
• CAS No.: 6134-79-8
• Molecular Formula: C8H9NO3
• Molecular Weight: 167.164
• Hs Code.: 2928000090
• Mol file: 6134-79-8.mol

Synonyms:Acetophenone,2',4'-dihydroxy-, oxime (6CI,7CI,8CI);2',4'-Dihydroxyacetophenone oxime;Methyl 2,4-dihydroxyphenyl ketoxime;NSC 402582;Resacetophenone oxime;

Chemical Property of 2,4-DIHYDROXYACETOPHENONE OXIME

Chemical Property:

• Vapor Pressure: 0.000357mmHg at 25°C
• Refractive Index: 1.653
• Boiling Point: 384.4 °C at 760 mmHg
• Flash Point: 244.8 °C
• PSA: 73.05000
• Density: 1.3 g/cm³
• LogP: 1.29600
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

(1E)-1-(2,4-Dihydroxyphenyl)ethanone oxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-DIHYDROXYACETOPHENONE OXIME

There total 4 articles about 2,4-DIHYDROXYACETOPHENONE OXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2',4'-dihydroxy-4-acetophenone (89-84-9) → 1-(2,4-dihydroxy-phenyl)-ethanone oxime (6134-79-8)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In water; at 100 ℃; for 6h;

Reference yield:

2',4'-dihydroxy-4-acetophenone (89-84-9) + hydroxylamine hydrochloride (5470-11-1) → 1-(2,4-dihydroxy-phenyl)-ethanone oxime (6134-79-8)

Guidance literature:

With sodium acetate; In 1,4-dioxane; water; at 20 ℃; for 72h;

Reference yield:

1-(2,4-dihydroxy-phenyl)-ethanone-(O-phenylcarbamoyl oxime ) → 1-(2,4-dihydroxy-phenyl)-ethanone oxime (6134-79-8) + aniline (62-53-3)

Guidance literature:

upstream raw materials:

2',4'-dihydroxy-4-acetophenone

hydroxylamine hydrochloride

Downstream raw materials:

C₁₄H₁₇NO₅

2',4'-dihydroxy-4-acetophenone

6-hydroxy-2-methylbenzoxazole

7-hydroxy-3-phenyl-2,3-dihydro-1H-pyrido<1,2-b><1,2>benzisoxazole-1,2-dicarboxylic acid

Refernces

• 1、 -. "Benzoxazole compound and application thereof". Paragraph 0063-0065. . Retrieved 2020/07/06.
• 2、 -. "7H - benzisoxazole and [7, 6 - e] [1, 3] oxazine derivative and application thereof". Paragraph 0016; 0020. . Retrieved 2017/08/14.