N-(1-phenylethyl)aniline

Base Information

• Chemical Name: N-(1-phenylethyl)aniline
• CAS No.: 779-54-4
• Molecular Formula: C14H15N
• Molecular Weight: 197.28
• Mol file: 779-54-4.mol

Synonyms:N-Phenyl-1-phenylethylamine;

Chemical Property of N-(1-phenylethyl)aniline

Chemical Property:

• PSA: 12.03000
• LogP: 3.93270

Purity/Quality:

95%, 99% ^*data from raw suppliers

N-(1-Phenylethyl)aniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: N-(1-Phenylethyl)aniline can be used as fungicides.

Technology Process of N-(1-phenylethyl)aniline

There total 219 articles about N-(1-phenylethyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenyl(1-phenylethylidene)amine (1749-19-5) → phenyl(1-phenylethyl)amine (779-54-4)

Guidance literature:

With potassium tert-butylate; hydrogen; potassium isopropoxide; [Ru((R,R)-cyP₂N₂)HCL]; at 20 ℃; for 36h; under 22801.5 Torr; Conversion of starting material;

Reference yield: 99.0%

N-(1-phenylethylidene)aniline (1749-19-5) → (R)-phenyl-(1-phenylethyl)amine (779-54-4,21232-36-0,21232-37-1,23652-68-8)

Guidance literature:

With (cyclooctadiene)(Ph₂PCH₂C(CH₃)2(C₃H₃NO)(tBu))Ir(tetrakis(3,5-(trifluoromethyl)phenyl)borate); hydrogen; In dichloromethane; at 20 ℃; under 37503.8 Torr; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.3762/bjoc.12.114

Reference yield: 99.0%

phenylacetylene (536-74-3) + aniline (62-53-3) → phenyl(1-phenylethyl)amine (779-54-4)

Guidance literature:

phenylacetylene; aniline; With indium(III) bromide; In toluene; at 110 ℃; for 3h; Inert atmosphere;

With Dimethylphenylsilane; In toluene; at 60 ℃; for 20h;

DOI:10.1002/ejoc.201402544

upstream raw materials:

styrene

aniline hydrochloride

phenyl(1-phenylethylidene)amine

aniline

Downstream raw materials:

phenyl-(1-phenyl-ethyl)-carbamic acid-(2-diethylamino-ethyl ester)

4''-methoxyphenyl (3S,αR)-3-[N-phenyl-N-(α-methylbenzyl)amino]-3-(3'-fluorophenyl)propanoate

4''-methoxyphenyl (3S,αR)-3-[N-phenyl-N-(α-methylbenzyl)amino]-3-(3'-pyridyl)propanoate

4''-methoxyphenyl (3S,αR)-3-[N-phenyl-N-(α-methylbenzyl)amino]-3-(3'-furyl)propanoate

Refernces

• 1、 Laborde, Coralie,Wei, Muh-Mei,Van Der Lee, Arie,Deydier, Eric,Daran, Jean-Claude,Volle, Jean-No?l,Poli, Rinaldo,Pirat, Jean-Luc,Manoury, Eric,Virieux, David. "Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes". . p. 12539 - 12545. Retrieved 2015.
• 2、 Huynh, Han Vinh,Seow, Hui Xian. "Synthesis and structural characterization of palladium dicarbene complexes bearing labile co-ligands". . p. 983 - 987. Retrieved 2009.
• 3、 Beller, Matthias,Gawande, Manoj B.,Jagadeesh, Rajenahally V.,Kadam, Ravishankar G.,Li, Xinmin,Ma, Zhuang,Petr, Martin,Zbo?il, Radek,Zhou, Bei. "Reusable Co-nanoparticles for general and selectiveN-alkylation of amines and ammonia with alcohols". . p. 111 - 117. Retrieved 2022/01/06.
• 4、 Barbazanges, Marion,Bories, Cassandre C.,Derat, Etienne,Petit, Marc. "Implication of a Silyl Cobalt Dihydride Complex as a Useful Catalyst for the Hydrosilylation of Imines". . p. 14262 - 14273. Retrieved 2021/11/27.