Bicyclo[4.1.0]hept-3-ene

Base Information

• Chemical Name: Bicyclo[4.1.0]hept-3-ene
• CAS No.: 16554-83-9
• Molecular Formula: C7H10
• Molecular Weight: 94.1564
• Mol file: 16554-83-9.mol

Synonyms:3-Norcarene(6CI,7CI,8CI); D3-Norcarene

Chemical Property of Bicyclo[4.1.0]hept-3-ene

Chemical Property:

• Vapor Pressure: 28.1mmHg at 25°C
• Boiling Point: 110.3°Cat760mmHg
• Flash Point: °C
• Density: 0.955g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicyclo[4.1.0]hept-3-ene

There total 10 articles about Bicyclo[4.1.0]hept-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

diiodomethane (75-11-6) + cyclohexa-1,4-diene (1165952-92-0) → 3-norcarene (16554-83-9)

Guidance literature:

copper; zinc;

DOI:10.1021/jo061865j

Reference yield:

cyclopropene (2781-85-3) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → 3-norcarene (16554-83-9)

Guidance literature:

at 0 ℃; for 2h;

DOI:10.1021/jo00283a018

Reference yield:

Δ3-Cyclohexencarbaldehyd-p-toluolsulfonylhydrazon (13428-09-6) → 3-norcarene (16554-83-9)

Guidance literature:

With sodium methylate; In diethylene glycol dimethyl ether; Heating;

DOI:10.1002/hlca.19680510502

upstream raw materials:

diiodomethane

cyclohexa-1,4-diene

Δ³-Cyclohexencarbaldehyd-p-toluolsulfonylhydrazon

4-Cyclohexenyldiazomethane

Downstream raw materials:

1,3,6-heptatriene

1,3-cycloheptadiene

bicyclo[4.1.0]hept-2-ene

3-Methylen-bicyclo<3.1.0>hexan

Refernces

• 1、 Austin, Rachel N.,Luddy, Kate,Erickson, Karla,Pender-Cudlip, Marilla,Bertrand, Erin,Deng, Dayi,Buzdygon, Ryan S.,Van Beilen, Jan B.,Groves, John T.. "Cage escape competes with geminate recombination during alkane hydroxylation by the diiron oxygenase AlkB". supporting information; experimental part. p. 5232 - 5234. Retrieved 2009/04/04.
• 2、 Newcomb, Martin,Chandrasena, R. Esala P.,Lansakara-P, Dharmika S. P.,Kim, Hye-Yeong,Lippard, Stephen J.,Beauvais, Laurance G.,Murray, Leslie J.,Izzo, Viviana,Hollenberg, Paul F.,Coon, Minor J.. "Desaturase reactions complicate the use of norcarane as a mechanistic probe. Unraveling the mixture of twenty-plus products formed in enzyme-catalyzed oxidations of norcarane". . p. 1121 - 1127. Retrieved 2007/10/03.