10H-Phenothiazine, 3-bromo-10-phenyl-

Base Information

• Chemical Name: 10H-Phenothiazine, 3-bromo-10-phenyl-
• CAS No.: 89922-57-6
• Molecular Formula: C18H12BrNS
• Molecular Weight: 354.27
• Mol file: 89922-57-6.mol

Synonyms:

Chemical Property of 10H-Phenothiazine, 3-bromo-10-phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10H-Phenothiazine, 3-bromo-10-phenyl-

There total 10 articles about 10H-Phenothiazine, 3-bromo-10-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

10-phenyl-10H-phenothiazine (7152-42-3) → 3-bromo-10-phenylphenothiazine (89922-57-6)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 20 ℃; for 2h; Cooling with ice;

Reference yield: 75.0%

bromobenzene (108-86-1,52753-63-6) + 3-bromo-10H-phenothiazine (3939-23-9) → 3-bromo-10-phenylphenothiazine (89922-57-6)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 2h; Reflux;

Reference yield: 56.0%

10-phenyl-10H-phenothiazine (7152-42-3) → 3-bromo-10-phenylphenothiazine (89922-57-6) + 3,7-dibromo-10-phenyl-10H-phenothiazine (89922-58-7) + 3,7-dibromo-10-(4-bromophenyl)-10H-phenothiazine (89922-59-8)

Guidance literature:

With bromine; In acetic acid; for 8h; Product distribution; Mechanism;

DOI:10.1021/jo00185a011

upstream raw materials:

10-phenyl-10H-phenothiazine

iodobenzene

3-bromo-10H-phenothiazine

10-phenylphenothiazinium perchlorate

Downstream raw materials:

10-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10H-phenothiazine

Refernces

• 1、 -. "Organic micromolecule material based on 2,6-dimethyl-4-cyanophenyl receptor unit, preparation and application". Paragraph 0028; 0032; 0033; 0060; 0062; 0065; 0066. . Retrieved 2018/10/19.
• 2、 -. "COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC LIGHT EMITTING DIODE INCLUDING THE SAME AND DISPLAY INCLUDING THE ORGANIC LIGHT EMITTING DIODE". Paragraph 0802-0805. . Retrieved 2016/10/10.