Hafniumiodide

Base Information Edit

Chemical Name:Hafniumiodide
CAS No.:13777-23-6
Molecular Formula:XHfI4
Molecular Weight:686.108
Hs Code.:2827600090
Nikkaji Number:J95.189G
Mol file:13777-23-6.mol

Synonyms:HAFNIUMIODIDE;AKOS025294448

Suppliers and Price of Hafniumiodide

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Hafnium(IV) iodide anhydrous, 99%
2g
$ 79.50

American Custom Chemicals Corporation
HAFNIUM(IV) IODIDE 95.00%
2G
$ 764.03

Total 14 raw suppliers

Chemical Property of Hafniumiodide Edit

Chemical Property:

Melting Point:400oC
Boiling Point:°C
PSA：0.00000
Density:5.6 g/mL at 25 °C(lit.)
LogP:3.54280
Sensitive.:Moisture Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:687.5644
Heavy Atom Count:5
Complexity:0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hafnium(IV) iodide anhydrous, 99% ^*data from reagent suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T
Statements: 61
Safety Statements: 36/37/39-45-53

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:[I-].[I-].[I-].[I-].[Hf+4]

Technology Process of Hafniumiodide

There total 4 articles about Hafniumiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.4%

: hafnium

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 13777-23-6
hafnium(IV) iodide

Guidance literature:: at 300 ℃; for 48h; Sealed tube; Glovebox; Inert atmosphere;
DOI:10.1002/zaac.201900297

Reference yield: 37.0%

: 13499-05-3
hafnium tetrachloride

: 13777-23-6
hafnium(IV) iodide

Guidance literature:: With hydrogen iodide; In diethyl ether; n-heptane; byproducts: LiCl, B2H6, H2; (Ar); ZrCl4 and LiBH4 were shaken in a Schlenk tube, dissolving in n-heptane at -78°C in vacuo, HBr was bubbled for 6 h at ambient temp.,stirring 12 h under HBr atmosphere; filtn., washed with n-heptane, dried in vacuo, sublimed at 170°C for 15 h, elem. anal.;
DOI:10.1039/DT9900001813