Bismuth(III)iodide

Base Information

• Chemical Name: Bismuth(III)iodide
• CAS No.: 7787-64-6
• Molecular Formula: BiI3
• Molecular Weight: 589.694
• Hs Code.: 2827600000
• UNII: BGX9X3FOLL
• Nikkaji Number: J43.712C
• Mol file: 7787-64-6.mol

Synonyms:Bismuth(III)iodide;NSC-103681;BISMUTH IODIDE [MI];BISMUTH IODIDE [WHO-DD];AKOS030228658;B5787

Chemical Property of Bismuth(III)iodide

Chemical Property:

• Appearance/Colour: White to yellowish white crystalline powder
• Melting Point: 408 °C(lit.)
• Boiling Point: 500°C
• Flash Point: 500°C
• PSA: 0.00000
• Density: 5.78 g/mL at 25 °C(lit.)
• LogP: 2.65710
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 589.6938
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [I-].[I-].[I-].[Bi+3]

Technology Process of Bismuth(III)iodide

There total 65 articles about Bismuth(III)iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bismuth (7440-69-9) + iodine (7553-56-2,12190-71-5,8031-47-8) → bismuth(III) iodide (7787-64-6)

Guidance literature:

In melt; passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;

Reference yield: 100.0%

acetyl iodide (507-02-8) + bismuth(III) chloride (7787-60-2) → bismuth(III) iodide (7787-64-6)

Guidance literature:

In benzene; slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;

DOI:10.1021/ja01615a024

Reference yield: 100.0%

BiO(1+)*I(1-)*2Bi2O3=BiOI*2Bi2O3 → bismuth(III) iodide (7787-64-6)

Guidance literature:

With oxonium; In not given; reaction of diluted acids with BiOI*2Bi2O3;;

upstream raw materials:

bismuth(III) oxide

aluminium(III) iodide

bismuth

iodine

Downstream raw materials:

bismuth(III) oxide iodide

bismuth(III) oxide

bismuth

bismuth(III) chloride

Refernces

• 1、 Nayak,Singh,Acharya. "CHARACTERIZATION OF As-GROWN AND IODINATED Bi2S3 THIN FILMS ON SILICON AND QUARTZ SUBSTRATES BY XRD.". . p. 455 - 459. Retrieved 1988.
• 2、 Egdell, R. G.,Hotokka, M.,Laaksonen, L.,Pyykkoe, P.,Snijders, J. G.. "". . p. 237 - 248. Retrieved 1982.
• 3、 Aliev,Babanly. "Solid-state equilibria and thermodynamic properties of compounds in the Bi-Te-I system". . p. 1076 - 1080. Retrieved 2008.
• 4、 Kim, Dae Gwi,Karasawa, Tsutomu,Komatsu, Teruo,Kobayashi, Takashi. "Exciton Transitions in Size-Distributed BiI3 Microcrystallites Embedded in CdI3 Crystals". . p. 3371 - 3378. Retrieved 1996.
• 5、 Watanabe, Katsuyoshi,Karasawa, Tsutomu,Komatsu, Teruo,Kaifu, Yozo. "Optical properties of extrinsic two-dimensional excitons in BiI3 single crystals". . p. 897 - 907. Retrieved 1986.
• 6、 Guenther, Anja,Steden, Folker,Ruck, Michael. "Syntheses, crystal structures, and triple twinning of the cluster trimers Bi2[PtBi6Br12]3 and Bi 2[PtBi6I12]3". . p. 423 - 430. Retrieved 2009/03/11.