L-Iditol

Base Information

• Chemical Name: L-Iditol
• CAS No.: 488-45-9
• Molecular Formula: C6H14 O6
• Molecular Weight: 182.174
• Hs Code.: 29054900
• European Community (EC) Number: 610-436-9
• UNII: 1Q2H9GC12E
• DSSTox Substance ID: DTXSID901337629
• Nikkaji Number: J92.811I
• Wikipedia: Iditol
• Wikidata: Q27102896
• Metabolomics Workbench ID: 41434
• Mol file: 488-45-9.mol

Synonyms:iditol;L-iditol

Chemical Property of L-Iditol

Chemical Property:

• Vapor Pressure: 7.22E-12mmHg at 25°C
• Melting Point: 77 °C
• Refractive Index: -3 ° (C=1, H2O)
• Boiling Point: 494.9°Cat760mmHg
• Flash Point: 292.6°C
• PSA: 121.38000
• Density: 1.596g/cm³
• LogP: -3.58540
• Storage Temp.: -20°C Freezer
• Solubility.: DMSO (Slightly, Sonicated), Methanol (Slightly), Water (Slightly, Sonicated)
• XLogP3: -3.1
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 182.07903816
• Heavy Atom Count: 12
• Complexity: 105

Purity/Quality:

98%, ^*data from raw suppliers

L-Iditol ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Alcohols and Polyols, Other
• Canonical SMILES: C(C(C(C(C(CO)O)O)O)O)O
• Isomeric SMILES: C([C@@H]([C@H]([C@@H]([C@H](CO)O)O)O)O)O
• Uses: Occurs naturally along with D-Glucitol in plants, including in the berry of mountain ash (Sorbus aucuparia). Allitol, D-talitol and L-iditol are sugar alcohols that are rare in nature.

Technology Process of L-Iditol

There total 85 articles about L-Iditol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.2%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + ethylene glycol (107-21-1) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 52505.3 Torr; Temperature; Pressure;

Reference yield: 33.6%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 45004.5 Torr; Temperature; Pressure;

Reference yield: 15.8%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With hydrogen; In water; at 239.84 ℃; for 4h; under 30003 Torr;

DOI:10.1039/c2gc35685f

upstream raw materials:

L-sorbose

glucose

L-iditol hexaacetate

2,3,4,6-tetra-O-benzyl-L-idopyranose

Downstream raw materials:

DL-glucitol hexa-acetate

O¹,O³;O²,O⁴;O⁵,O⁶-trimethanediyl-DL-glucitol

(S)-3-(4-methoxybenzyloxy)-2-methoxyethoxymethoxypropanal

formaldehyd

Refernces

• 1、 Tindall, Daniel J.,Mader, Steffen,Kindler, Alois,Rominger, Frank,Hashmi, A. Stephen K.,Schaub, Thomas. "Selective and Scalable Synthesis of Sugar Alcohols by Homogeneous Asymmetric Hydrogenation of Unprotected Ketoses". supporting information. p. 721 - 725. Retrieved 2020/10/19.
• 2、 Guo, Jiaxing,He, Minyao,Li, Cuiqing,Liu, ShanShan,Song, Yongji,Wang, Hong,Wang, Xincheng. "Direct conversion of cellulose into isosorbide over Ni doped NbOPO4catalysts in water". supporting information. p. 10292 - 10299. Retrieved 2020/07/14.