Bismuthtrichloride

Base Information

• Chemical Name: Bismuthtrichloride
• CAS No.: 7787-60-2
• Molecular Formula: BiCl3
• Molecular Weight: 315.339
• UNII: 4X6566U3SD
• Nikkaji Number: J43.711E
• Mol file: 7787-60-2.mol

Synonyms:BISMUTHTRICHLORIDE;Bismuth chloride [WHO-DD];BISMUTH CHLORIDE [MI];AKOS030228659;B3546

Chemical Property of Bismuthtrichloride

Chemical Property:

• Appearance/Colour: White crystal and crystalline powder
• Melting Point: 230-232 °C(lit.)
• Boiling Point: 447oC
• Flash Point: 430°C
• PSA: 0.00000
• Density: 4.75 g/cm³
• LogP: 2.06850
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 313.88696
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: S26:; S37/39:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Bi+3]

Technology Process of Bismuthtrichloride

There total 124 articles about Bismuthtrichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

hydrogenchloride (7647-01-0,15364-23-5) + bismuth(III) oxide (1304-76-3) → bismuth(III) chloride (7787-60-2)

Guidance literature:

In acetic acid; byproducts: H2O;

Reference yield: 100.0%

bismuth (7440-69-9) + chlorine (7782-50-5) → bismuth(III) chloride (7787-60-2)

Guidance literature:

In melt; passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;

Reference yield: 99.0%

tri(naphthalen-1-yl)bismuth (33397-22-7) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-benzoylnaphthalene (642-29-5) + bismuth(III) chloride (7787-60-2)

Guidance literature:

With aluminium trichloride; benzoic acid; In chloroform; 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1;

upstream raw materials:

trimethylamine hydrochloride

triphenylbismuthane

phosgene

hydrogenchloride

Downstream raw materials:

bismuth(III) iodide

triphenylbismuthane

BiCl₅^(2-)

bismuth(III)

Refernces

• 1、 Welch, Eric J.,Crawford, Nathan R. M.,Bergman, Robert G.,Long, Jeffrey R.. "New routes to transition metal-carbido species: Synthesis and characterization of the carbon-centered trigonal prismatic clusters [W 6CCl18]n- (n = 1, 2, 3)". . p. 11464 - 11465. Retrieved 2003.
• 2、 Chauhan, H. P. S.,Srivastava, G.,Mehrotra, R. C.. "". . p. 1337 - 1346. Retrieved 1984.
• 3、 Stroebele, Markus,Meyer, H.-Juergen. "Constitutional isomerism of BiW6Cl15: (BiCl)[W 6Cl14] and (BiCl2)[W6Cl 13]". . p. 1517 - 1519. Retrieved 2009.
• 4、 Petasch,Oppermann. "Investigations on the pseudobinary system Bi2Se3/BiCl3". . p. 169 - 173. Retrieved 1997.
• 5、 Hempel. "". . p. 496 - 496. Retrieved 1881.
• 6、 Peng, Yan-Hong,Sun, Shao-Fa. "Synthesis, structure and properties of the first hybrid Bi 2Cl93- supramolecular compound based on macrocyclic rotator-stator assembly". . p. 29 - 32. Retrieved 2012.
• 7、 Beck, Johannes,Eck, Steffen J.. "The bicyclic polyselenium cation Se102+ in the structure of Se10[Bi4Cl14]". . p. 1910 - 1912. Retrieved 2011/01/05.