VANADIUM OXIDE

Base Information

• Chemical Name: VANADIUM OXIDE
• CAS No.: 12035-98-2
• Deprecated CAS: 12137-29-0,2583498-14-8
• Molecular Formula: VO
• Molecular Weight: 66.9409
• Hs Code.: 28253090
• European Community (EC) Number: 234-834-3
• DSSTox Substance ID: DTXSID6065189
• Wikipedia: Vanadium(II) Oxide,Vanadium(II)_oxide
• Wikidata: Q1966236
• Mol file: 12035-98-2.mol

Synonyms:Vanadiummonoxide;Vanadium monoxide (VO);

Chemical Property of VANADIUM OXIDE

Chemical Property:

• Appearance/Colour: grey solid with metallic lustre
• Melting Point: 1789 °C
• Boiling Point: 2627 °C at 760mmHg
• PSA: 17.07000
• Density: 5.758 g cm³
• LogP: -0.11880
• Water Solubility.: soluble acids [KIR83]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 66.938872
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: O=[V]

Technology Process of VANADIUM OXIDE

There total 57 articles about VANADIUM OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminium nitride + vanadia → aluminum oxide (1333-84-2,1344-28-1) + vanadium(II) oxide (12035-98-2)

Guidance literature:

In neat (no solvent, solid phase); byproducts: NO, NO2; mixt. of AlN, V2O5 with molar ratio of 7.44 heated at 1100°C; identified by X-ray diffraction;

DOI:10.1134/S0020168511030071

Reference yield:

aluminium nitride + vanadia → aluminum oxide (1333-84-2,1344-28-1) + vanadium(II) oxide (12035-98-2) + vanadium nitride

Guidance literature:

In neat (no solvent, solid phase); byproducts: NO, NO2; mixt. of AlN, V2O5 with molar ratio of 9.00 or 5.66 or 4.00 heated at 1600°C; identified by X-ray diffraction;

DOI:10.1134/S0020168511030071

Reference yield:

aluminium nitride + vanadia → aluminum oxide (1333-84-2,1344-28-1) + vanadium(II) oxide (12035-98-2) + vanadium nitride + AlV2O4 + AlV3

Guidance literature:

In neat (no solvent, solid phase); byproducts: NO, NO2; mixt. of AlN, V2O5 with molar ratio of 2.33 heated at 1600°C; identified by X-ray diffraction;

DOI:10.1134/S0020168511030071

upstream raw materials:

vanadium

oxygen

vanadium(V) oxychloride

triethylstannane

Downstream raw materials:

nickel

vanadium(V) oxychloride

vanadium

carbon monoxide

Refernces

• 1、 Harrington, Joel,Weisshaar, James C.. "". . p. 2809 - 2812. Retrieved 1992.
• 2、 Kang, Z. C.,Eyring, L.. "". . p. 343 - 354. Retrieved 1992.
• 3、 Kauffmann, J. W.,Hauge, R. H.,Margrave, J. L.. "Reactions of Atomic Scandium, Titanium, and Vanadium with Molecular Water at 15 K". . p. 3547 - 3552. Retrieved 1985.
• 4、 Chumarev,Mar'evich,Larionov,Dubrovskii, A. Ya.. "Reactions of V2O5, Nb2O5, and Ta2O5 with AlN". . p. 267 - 272. Retrieved 2011.
• 5、 Vondrak, J.,Bludska, J.,Belan, V. N.,Lazarev, V. B.,Bogatov, Yu. E.. "". . p. 17 - 24. Retrieved 1990.
• 6、 Bridges,Greedan. "Phase transitions and electrical transport in the mixed-valence V 2+/V3+ oxide BaV10O15". . p. 1098 - 1110. Retrieved 2004.
• 7、 McQuaid, M. J.,Morris, K.,Gole, J. L.. "Trends in the Optical Signatures for Transition-Metal Oxide Carbonyl Complexes. Evaluation of Transition-Metal Carbonyl, M(CO)x, Binding Energies". . p. 5280 - 5285. Retrieved 1988.
• 8、 Valeeva,Schroettner,Rempel. "Preparation of nanocrystalline VOy by high-energy ball milling". . p. 408 - 411. Retrieved 2011.
• 9、 Mahmoud, Marwa A.,Zaitone, Sawsan A.,Ammar, Alaa M.,Sallam, Shehab A.. "Synthesis, spectral, thermal and insulin-enhancing properties of oxovanadium(IV) complexes of metformin Schiff-bases". . p. 957 - 969. Retrieved 2017.
• 10、 Cowin, Peter I.,Lan, Rong,Petit, Christophe T.G.,Zhang, Lei,Tao, Shanwen. "Conductivity and stability of cobalt pyrovanadate". . p. 4117 - 4121. Retrieved 2011.