Phenyl acrylate

Base Information

• Chemical Name: Phenyl acrylate
• CAS No.: 937-41-7
• Molecular Formula: C9H8O2
• Molecular Weight: 148.161
• Hs Code.: 29161290
• European Community (EC) Number: 213-329-1
• UNII: N76Z7HU35P
• DSSTox Substance ID: DTXSID5061328
• Nikkaji Number: J298.528D
• Wikidata: Q72498407
• Mol file: 937-41-7.mol

Synonyms:Phenyl acrylate;937-41-7;phenyl prop-2-enoate;2-PROPENOIC ACID, PHENYL ESTER;Acrylic Acid Phenyl Ester;N76Z7HU35P;EINECS 213-329-1;MFCD00048145;AI3-15711;Phenyl acrylate,min. 95%;phenol acrylate;phenyl-acrylate;PHENYL 2-PROPENOATE;UNII-N76Z7HU35P;SCHEMBL28916;DTXSID5061328;AC8636;Phenyl acrylate, stabilized with BHT;AKOS005206789;CS-W016338;FS-4899;SY050025;FT-0633150;P2268;EN300-6889920;Acrylic acid phenyl ester, 97%, stabilized with BHT

Chemical Property of Phenyl acrylate

Chemical Property:

• Vapor Pressure: 0.0596mmHg at 25°C
• Refractive Index: 1.5210
• Boiling Point: 232.2 °C at 760 mmHg
• Flash Point: 88.3 °C
• PSA: 26.30000
• Density: 1.068 g/cm³
• LogP: 1.77800
• Storage Temp.: 2-8°C
• Water Solubility.: Insoluble in water.
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 148.052429494
• Heavy Atom Count: 11
• Complexity: 146

Purity/Quality:

99% ^*data from raw suppliers

PhenylAcrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.; R51/53:Toxic to aquatic organisms, may cause long-term advers
• Hazard Codes: R36/37/38:Irritating to eyes, respiratory system and skin.; R51/53:Toxic to aquatic organisms, may cause long-term advers
• Statements: 36/37/38-51/53
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OC1=CC=CC=C1
• Uses: Phenyl acrylate reacts with benzaldehyde to produce 2-(hydroxy-phenyl-methyl)-acrylic acid phenyl ester.

Technology Process of Phenyl acrylate

There total 29 articles about Phenyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

vinyl acetate (108-05-4,9003-20-7) + phenol (108-95-2,27073-41-2) → phenyl acrylate (937-41-7)

Guidance literature:

With rubidium fluoride; In acetonitrile; at 80 ℃; for 0.75h;

DOI:10.1007/s00706-013-1019-2

Reference yield: 100.0%

C12H17O2Si*2CO*Fe*NO → phenyl acrylate (937-41-7)

Guidance literature:

With hydrogenchloride;

DOI:10.1246/bcsj.64.2965

Reference yield: 98.0%

phenyl 2,3-dibromopropanoate (124654-80-4) → phenyl acrylate (937-41-7)

Guidance literature:

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; sodium carbonate; In dimethyl sulfoxide; at 20 ℃; for 2.5h; Inert atmosphere; Irradiation;

DOI:10.1002/chem.201601819

upstream raw materials:

pyridine

3-chloropropionic acid phenyl ester

acrylic acid

phenol

Downstream raw materials:

7-hydroxy-indan-1-one

acetylene

phenyl cyclohex-3-enecarboxylate

((Z)-3-Iodo-1-phenoxy-propenyloxy)-trimethyl-silane

Refernces

• 1、 Sun, Jin-Sheng,Du, Wei-Chao,Pu, Xiao-Lin,Zou, Zhuan-Zheng,Zhu, Bo-Bo. "Synthesis and evaluation of a novel hydrophobically associating polymer based on acrylamide for enhanced oil recovery". . p. 1598 - 1607. Retrieved 2015.
• 2、 Das, Animesh,Jana, Akash,Maji, Biplab. "Palladium-catalyzed remote C-H functionalization of 2-aminopyrimidines". supporting information. p. 4284 - 4287. Retrieved 2020/04/27.
• 3、 -. "CARBOXYLIC ACID ESTER PRODUCTION METHOD". Paragraph 0071; 0072; 0074. . Retrieved 2019/01/04.