Carbonyl chloride fluoride

Base Information

• Chemical Name: Carbonyl chloride fluoride
• CAS No.: 353-49-1
• Molecular Formula: CClFO
• Molecular Weight: 82.4618
• European Community (EC) Number: 206-533-7
• DSSTox Substance ID: DTXSID8073897
• Nikkaji Number: J193.825H
• Wikidata: Q82002483
• Mol file: 353-49-1.mol

Synonyms:Carbonyl chloride fluoride;Carbonic chloride fluoride;353-49-1;EINECS 206-533-7;CARBONYLCHLORIDEFLUORIDE;CClFO;COClF;Fluorochloromethanone;Carbonyl chlorofluoride;C-Cl-F-O;Carbonyl chloride fluoride 97%;DTXSID8073897;MFCD00042118;Estra-1,3,5(10), 7-tetraen-17-one, 3-hydroxy-;Cholan-24-oic acid, 3,7-dihydroxy-, (3a,5.beta.,7a)-

Chemical Property of Carbonyl chloride fluoride

Chemical Property:

• Vapor Pressure: 392mmHg at 25°C
• Melting Point: -138 °C
• Refractive Index: 1.32
• Boiling Point: 42.4 °C at 760 mmHg
• PSA: 17.07000
• Density: 1.397 g/cm³
• LogP: 1.31470
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 81.9621705
• Heavy Atom Count: 4
• Complexity: 35

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C; F
• Hazard Codes: C,F
• Statements: 8-34
• Safety Statements: 3/7-9-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(F)Cl

Technology Process of Carbonyl chloride fluoride

There total 58 articles about Carbonyl chloride fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phosgene (75-44-5) + sodium fluoride (7681-49-4) → Carbonyl fluoride (353-50-4) + fluoroformyl chloride (353-49-1) + carbon dioxide (124-38-9,18923-20-1) + silicon tetrafluoride (7783-61-1)

Guidance literature:

In acetonitrile; condensation, 20°C in a sealed Pyrex tube, staying 24 h at 20°C;

Reference yield: 40.0%

tetrafluorohydrazine (10036-47-2) + oxalyl dichloride (79-37-8) → phosgene (75-44-5) + chlorodifluoroamine (13637-87-1) + dinitrogen difluoride (10578-16-2) + fluoroformyl chloride (353-49-1) + difluorocarbamoyl chloride (16847-30-6)

Guidance literature:

other Radiation; UV photolysis, 6h, ratio of educts: (ClCO)2 112 Torr, N2F4 168 Torr; fractionated condensation, gaschromy.;

Reference yield: 15.6%

Chlorodifluoromethane (75-45-6) → phosgene (75-44-5) + Carbonyl fluoride (353-50-4) + fluoroformyl chloride (353-49-1)

Guidance literature:

With oxygen; for 0.5 - 4.5h; Product distribution / selectivity; UV-irradiation (500 W);

upstream raw materials:

phosgene

Dichlorofluoromethane

1,1,3,3-tetrachloro-1,3-difluoro-2-propanone

trichlorofluoromethane

Downstream raw materials:

ethyl fluoroformate

Diethyl carbonate

methyl-phenyl-carbamoyl fluoride

3.4.5-Trimethoxy-benzyloxycarbonyl-fluorid

Refernces

• 1、 Tyerman. "". . p. 392. Retrieved 1968.
• 2、 Young,Dresdner. "". . p. 1576. Retrieved 1958.
• 3、 Simons,Herman,Pearlson. "-". . p. 1672,1673. Retrieved 1946.
• 4、 -. "Production of carbonyl fluoride". Page/Page column 3; 4. . Retrieved 2008/06/13.