1-Tridecene

Base Information

• Chemical Name: 1-Tridecene
• CAS No.: 2437-56-1
• Molecular Formula: C13H26
• Molecular Weight: 182.349
• Hs Code.: 2901299090
• European Community (EC) Number: 219-443-8
• NSC Number: 78473
• UNII: 5B0U2S314C
• DSSTox Substance ID: DTXSID3029235
• Nikkaji Number: J44.101E
• Wikidata: Q27162003
• Metabolomics Workbench ID: 5029
• ChEMBL ID: CHEMBL3186542
• Mol file: 2437-56-1.mol

Synonyms:1-tridecene;n-tridec-1-ene;tridecene

Chemical Property of 1-Tridecene

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 0.0856mmHg at 25°C
• Melting Point: −23 °C(lit.)
• Boiling Point: 233.3°Cat760mmHg
• Flash Point: 79.4°C
• PSA: 0.00000
• Density: 0.765g/cm³
• LogP: 5.09330
• XLogP3: 7.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 182.203450829
• Heavy Atom Count: 13
• Complexity: 94.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Other Organic Compounds
• Canonical SMILES: CCCCCCCCCCCC=C

Technology Process of 1-Tridecene

There total 53 articles about 1-Tridecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-butyldec-9-enenitrile (1036741-77-1) → 1-tridecene (2437-56-1)

Guidance literature:

With potassium; tert-butyl alcohol; In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; at 0 ℃; for 3h;

DOI:10.1021/jo800640j

Reference yield: 89.0%

diiodomethane (75-11-6) + Dodecanal (112-54-9) → 1-tridecene (2437-56-1)

Guidance literature:

With trimethylaluminum; zinc; In tetrahydrofuran; at 25 ℃; for 2h;

DOI:10.1016/S0040-4039(01)80893-5

Reference yield: 88.0%

n-tetradecanoic acid (544-63-8) → 1-tridecene (2437-56-1)

Guidance literature:

With nickel(II) iodide; triphenylphosphine; In neat (no solvent); for 16h; under 0.5 Torr; Reagent/catalyst; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.organomet.6b00940

upstream raw materials:

n-decyl magnesium bromide

allyl bromide

diiodomethane

Dodecanal

Downstream raw materials:

2-methylpentadecanoic acid

2-azido-2-[(4R,5S)-2,2-dimethyl-5-[(E)-1-(4-methylphenylsulfanyl)-3-tetradecenyl]-1,3-dioxolan-4-yl]ethyl benzyl ether

tetradecan-2-one

(2S,3R,5R)-3-{(tert-butyldimethylsilyl)oxy}-2-[{(tert-butyldimethylsilyl)oxy}methyl]-1-{(2-nitrophenyl)sulfonyl}-5-[(1E)-(tridec-1-en-1-yl)]pyrrolidine

Refernces

• 1、 Entwistle,I.D.,Johnstone,R.A.W.. "-". . p. 29 - 30. Retrieved 1965.
• 2、 -. "A Method for preparing alpha-olefins from Biomass-derived fat and oil". Paragraph 0191-0202; 0239-0242. . Retrieved 2020/09/22.
• 3、 Lu, Chen,Shen, Fenglin,Wang, Shuaibo,Wang, Yuyang,Liu, Juan,Bai, Wen-Ju,Wang, Xiqing. "An Engineered Self-Sufficient Biocatalyst Enables Scalable Production of Linear α-Olefins from Carboxylic Acids". . p. 5794 - 5798. Retrieved 2018/06/01.