Neodymium(III) chloride

Base Information

• Chemical Name: Neodymium(III) chloride
• CAS No.: 10024-93-8
• Molecular Formula: NdCl3
• Molecular Weight: 250.599
• Hs Code.: 28273985
• UNII: 25O44EQD4O
• Nikkaji Number: J43.918E
• Wikipedia: Neodymium(III) chloride,Neodymium(III)_chloride
• Mol file: 10024-93-8.mol

Synonyms:Neodymium(III) chloride;NEODYMIUM(3+) CHLORIDE;ATINCSYRHURBSP-UHFFFAOYSA-K;AKOS024256090;SY061229;E70016

Chemical Property of Neodymium(III) chloride

Chemical Property:

• Appearance/Colour: mauve colored hygroscopic solid
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 784 °C(lit.)
• Boiling Point: 1600°C (estimate)
• PSA: 0.00000
• Density: 4.134 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water and ethanol.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 246.81429
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Neodymium(III) chloride, anhydrous (99.9%-Nd) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Nd+3]
• Uses: Neodymium Chloride mainly used for glass, crystal and capacitors. Colours glass delicate shades ranging from pure violet through wine-red and warm gray. Light transmitted through such glass shows unusually sharp absorption bands. It is useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens. It is highly valued in glass manufacturing for its attractive purple coloring to glass. Neodymium(III) chloride is used as a precursor for the production of neodymium metal. It is used as a catalyst and accelerates polymerization of various dienes such as polybutylene, polybutadiene, and polyisoprene. It has luminescence property and is widely used as fluorescent label in organic molecules, thereby helping in easy tracking of the compound using fluorescence microscope during various physical and chemical reactions.

Technology Process of Neodymium(III) chloride

There total 37 articles about Neodymium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + neodymium(III) oxide → neodymium trichloride (10024-93-8)

Guidance literature:

In hydrogenchloride; metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2;

DOI:10.1081/SIM-120003800

Reference yield: 36.75%

erbium(III) oxide + neodymium(III) oxide + potassium chloride + chlorine (7782-50-5) → erbium(III) chloride (10138-41-7) + neodymium trichloride (10024-93-8)

Guidance literature:

With pyrographite; In gas; byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Nd2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;

DOI:10.1016/j.jallcom.2005.02.104

Reference yield: 13.0%

neodymium(III) oxide + aluminium chloride dimer → aluminum oxochloride + neodymium trichloride (10024-93-8)

Guidance literature:

In neat (no solvent); Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 500°C (Cl2); chemical vapour phase transport with Al2Cl6 from 500 to 400°C, 24 h;

upstream raw materials:

neodymium(III) chloride hydrate

chlorine

thionyl chloride

aluminium trichloride

Downstream raw materials:

sodium chloride

Refernces

• 1、 Sharma, Ram A.. "Phase equilibria in rare-earth chloride-fluoride and rare-earth chloride-magnesium fluoride systems". . p. 2582 - 2586. Retrieved 1996.
• 2、 Meshkova,Matiichuk,Potopnyk,Topilova,Gorodnyuk,Olenich,Bol'Bot. "IR luminescence of neodymium(III) and ytterbium(III) complexes with acylpyrazolones in solutions". . p. 899 - 905. Retrieved 2011.
• 3、 Massaux, J.,Duyckaerts, G.. "". . p. 416 - 419. Retrieved 1974.
• 4、 Hu, Bin,Chen, Da,Su, Qingde. "Photoacoustic phase study on the frequency dependence of phase angle and triplet state lifetime of Nd(III)-acetylacetonate". . p. 55 - 59. Retrieved 2006.
• 5、 Sun, Li-Ning,Zhang, Hong-Jie,Meng, Qing-Guo,Liu, Feng-Yi,Fu, Lian-She,Peng, Chun-Yun,Yu, Jiang-Bo,Zheng, Guo-Li,Wang, Shu-Bin. "Near-infrared luminescent hybrid materials doped with lanthanide (Ln) complexes (Ln = Nd, Yb) and their possible laser application". . p. 6174 - 6182. Retrieved 2005.
• 6、 Yifeng, Zhang,Dianpeng, Sui,Xuebing, Huang,Shulan, Wang. "The Investigation of Conductivity of Liquid NdCl3-LiCl-KCl System by Mixture Design". . p. 1115 - 1118. Retrieved 1995.
• 7、 Velchuri, Radha,Kumar, B. Vijaya,Devi, V. Rama,Prasad,Prakash, D. Jaya,Vithal. "Preparation and characterization of rare earth orthoborates, LnBO 3 (Ln = Tb, La, Pr, Nd, Sm, Eu, Gd, Dy, Y) and LaBO3:Gd, Tb, Eu by metathesis reaction: ESR of LaBO3:Gd and luminescence of LaBO3:Tb, Eu". . p. 1219 - 1226. Retrieved 2011.
• 8、 Ma,Wang,Shi. "Synthesis and characterization of lanthanide(III) Schiff base complexes derived from cysteine and benzoin". . p. 617 - 627. Retrieved 2002.
• 9、 Lissner, Falk,Schleid, Thomas. "The oxide nitride selenides M3ONSe2 of trivalent lanthanoids (M = Ce - Nd)". . p. 2799 - 2804. Retrieved 2008.
• 10、 Adachi, Gin-ya,Murase, Kuniaki,Shinozaki, Kiyoshi,Machida, Ken-ichi. "Mutual Separation Characteristics for Lanthanoid Elements via Gas Phase Complexes with Alkaline Chlorides". . p. 511 - 514. Retrieved 1992.