Carbamic acid, (butyldimethylsilyl)methyl ester

Base Information

• Chemical Name: Carbamic acid, (butyldimethylsilyl)methyl ester
• CAS No.: 3124-39-8
• Molecular Formula: C₈H₁₉NO₂Si
• Molecular Weight: 189.33
• NSC Number: 96820
• DSSTox Substance ID: DTXSID20953307
• Wikidata: Q82932114
• Mol file: 3124-39-8.mol

Synonyms:3124-39-8;Carbamic acid, (butyldimethylsilyl)methyl ester;(Butyldimethylsilyl)methanol carbamate;BRN 2412252;Methanol, (butyldimethylsilyl)-, carbamate;(Butyldimethylsilyl)methyl ester of carbamic acid;DTXSID20953307;NSC96820;NSC 96820;NSC-96820;(BUTYLDIMETHYLSILYL)METHYL CARBAMATE;[Butyl(dimethyl)silyl]methyl hydrogen carbonimidate

Chemical Property of Carbamic acid, (butyldimethylsilyl)methyl ester

Chemical Property:

• Vapor Pressure: 0.00256mmHg at 25°C
• Boiling Point: 286.9°C at 760 mmHg
• Flash Point: 127.3°C
• Density: 0.93g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 189.118505383
• Heavy Atom Count: 12
• Complexity: 148

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Si](C)(C)COC(=O)N

Technology Process of Carbamic acid, (butyldimethylsilyl)methyl ester

There total 3 articles about Carbamic acid, (butyldimethylsilyl)methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-Butyl-chlormethyl-dimethylsilan (3121-75-3) → Carbaminsaeure-(butyldimethylsilylmethylester) (3124-39-8)

Guidance literature:

Multi-step reaction with 3 steps

1: KOAc

2: LiAlH₄

3: (i) Py, (ii) liq. NH₃

With lithium aluminium tetrahydride; potassium acetate;

DOI:10.1021/jm00329a012

Reference yield:

Acetoxymethyl-butyl-dimethylsilan (2917-62-6) → Carbaminsaeure-(butyldimethylsilylmethylester) (3124-39-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄

2: (i) Py, (ii) liq. NH₃

With lithium aluminium tetrahydride;

DOI:10.1021/jm00329a012

Reference yield:

Butyldimethylsilylmethanol (2917-54-6) + phenyl chloroformate (1885-14-9) → Carbaminsaeure-(butyldimethylsilylmethylester) (3124-39-8)

Guidance literature:

Multistep reaction; (i) Py, (ii) liq. NH₃;

DOI:10.1021/jm00329a012

upstream raw materials:

Butyldimethylsilylmethanol

phenyl chloroformate

n-Butyl-chlormethyl-dimethylsilan

Acetoxymethyl-butyl-dimethylsilan

Refernces