CHLOROMETHYLDIMETHYL-N-BUTYLSILANE

Base Information

• Chemical Name: CHLOROMETHYLDIMETHYL-N-BUTYLSILANE
• CAS No.: 3121-75-3
• Molecular Formula: C7H17 Cl Si
• Molecular Weight: 164.75
• Hs Code.: 2931900090
• Mol file: 3121-75-3.mol

Synonyms:(Chloromethyl)dimethylbutylsilane;Butyl(chloromethyl)dimethylsilane; n-Butyl(chloromethyl)dimethylsilane

Chemical Property of CHLOROMETHYLDIMETHYL-N-BUTYLSILANE

Chemical Property:

• PSA: 0.00000
• LogP: 3.69120

Purity/Quality:

98%,99%, ^*data from raw suppliers

CHLOROMETHYLDIMETHYL-N-BUTYLSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHLOROMETHYLDIMETHYL-N-BUTYLSILANE

There total 7 articles about CHLOROMETHYLDIMETHYL-N-BUTYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

o-Bromphenyl-chlormethyldimethylsilylether (84998-62-9) → n-Butyl-chlormethyl-dimethylsilan (3121-75-3) + 3,3-dimethyl-2,3-dihydrobenzo[d][1,3]oxasilole (84998-63-0)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; 1.) 20 deg C, 1 h, 2.) reflux, 2 d;

DOI:10.1016/0022-328X(83)80214-9

Reference yield: 29.0%

n-butyllithium (109-72-8,29786-93-4) + o-Bromphenyl-chlormethyldimethylsilylether (84998-62-9) → n-Butyl-chlormethyl-dimethylsilan (3121-75-3) + 3,3-dimethyl-2,3-dihydrobenzo[d][1,3]oxasilole (84998-63-0)

Guidance literature:

In diethyl ether; hexane; 1.) 20 deg C, 1 h, 2.) reflux, 2 d;

DOI:10.1016/0022-328X(83)80214-9

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + Chloro(chloromethyl)dimethylsilane (1719-57-9) → n-Butyl-chlormethyl-dimethylsilan (3121-75-3)

Guidance literature:

In tetrahydrofuran; hexane;

DOI:10.1016/S0022-328X(00)92420-3

upstream raw materials:

Chloro(chloromethyl)dimethylsilane

butyl magnesium bromide

n-butyllithium

bis(chloromethyl)(methyl)chlorosilane

Downstream raw materials:

Acetoxymethyl-butyl-dimethylsilan

Carbaminsaeure-(butyldimethylsilylmethylester)

Butyldimethylsilylmethanol

Refernces

• 1、 Heinicke, J.,Nietzschmann, E.,Tzschach, A.. "SYNTHESE UND UMLAGERUNGSREAKTIONEN VON o-FUNKTIONELLEN PHENYLLITHIUM- UND PHENYLNATRIUM DERIVATEN DER IVB UND VB-ELEMENTE". . p. 1 - 8. Retrieved 2007/10/02.