DIPHENYL(VINYL)PHOSPHINE OXIDE

Base Information

• Chemical Name: DIPHENYL(VINYL)PHOSPHINE OXIDE
• CAS No.: 2096-78-8
• Molecular Formula: C14H13OP
• Molecular Weight: 228.23
• Hs Code.: 2902909090
• Mol file: 2096-78-8.mol

Synonyms:Phosphine oxide, diphenylvinyl-;Diphenylvinylphosphine oxide;(Ethenyl-phenyl-phosphoryl)benzene;Phosphine oxide, ethenyldiphenyl-;Ethenyl(diphenyl)phosphane oxide;

Chemical Property of DIPHENYL(VINYL)PHOSPHINE OXIDE

Chemical Property:

• Vapor Pressure: 3.59E-06mmHg at 25°C
• Melting Point: 115-117 °C
• Refractive Index: 1.571
• Boiling Point: 397.6 °C at 760 mmHg
• Flash Point: 194.3 °C
• PSA: 26.88000
• Density: 1.11 g/cm³
• LogP: 3.14400

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Ethenyldiphenylphosphine Oxide was used a starting material in the synthesis of sorbents for the selective and effective sorption of Am(III) from HNO3 solutions containing high concentration of Fe(III) and Zr(IV).

Technology Process of DIPHENYL(VINYL)PHOSPHINE OXIDE

There total 44 articles about DIPHENYL(VINYL)PHOSPHINE OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

diphenyl(vinyl)phosphine sulfide (21776-15-8) → vinyldiphenylphosphine oxide (2096-78-8)

Guidance literature:

With iodosylbenzene; Montmorillonite K₁₀; In acetonitrile; at 20 ℃; for 1h;

DOI:10.1055/s-2001-12312

Reference yield: 92.0%

2-(Hexylselanyl)ethyl(diphenyl)phosphine selenide (1092730-03-4) → vinyldiphenylphosphine oxide (2096-78-8)

Guidance literature:

With dihydrogen peroxide; In water; acetone; at 44 - 56 ℃; for 15h;

DOI:10.1016/j.mencom.2010.01.008

Reference yield: 91.3%

Diphenylvinylphosphine (2155-96-6) → vinyldiphenylphosphine oxide (2096-78-8)

Guidance literature:

With dihydrogen peroxide; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/acs.oprd.9b00559

upstream raw materials:

diphenyl(β-chloroethyl)phosphine oxide

Ethyl diphenylphosphinite

ethylene dibromide

vinyl magnesium bromide

Downstream raw materials:

cis-6,6-dimethyl-3-diphenylphosphinylhexahydropyrrolo<1,2-b>isoxazole

cis-6,6-dimethyl-2-diphenylphosphinylhexahydropyrrolo<1,2-b>isoxazole

phenylbis(β-diphenylphosphorylethyl)phosphine

1,4,7-tris(β-diphenylphosphinylethyl)-1,4,7-triazacyclononane

Refernces

• 1、 Berlin,Butler. "-". . p. 2537. Retrieved 1961.
• 2、 Yarkevich,Turanov,Kharitonov. "Synthesis and extractive properties of dialkylaminomethyl-substituted dialkylamides of diphenylphosphinoylacetic acid". . p. 1050 - 1056. Retrieved 2005.
• 3、 Dziuba, Kamil,Frynas, S?awomir,Szwaczko, Katarzyna. "Knoevenagel Condensation of Phosphinoylacetic Acids with Aldehydes: An Efficient One-Pot Strategy for the Synthesis of P-Functionalized Alkenyl Compounds". . p. 2142 - 2154. Retrieved 2021/01/21.
• 4、 Artyushin, Oleg I.,Belus', Svetlana K.,Bondarenko, Natalia A.,Tcarkova, Kseniia V.. "New method for the syntheses of 2-aminoethyldiphenylphosphine oxides under the phase transfer conditions using cesium carbonate". . . Retrieved 2021/12/02.