CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE

Base Information

• Chemical Name: CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE
• CAS No.: 1481-41-0
• Molecular Formula: C5H10ClF3Si
• Molecular Weight: 190.668
• Hs Code.: 2931900090
• European Community (EC) Number: 216-039-3
• DSSTox Substance ID: DTXSID7061722
• Nikkaji Number: J206.683A
• Wikidata: Q72449642
• Mol file: 1481-41-0.mol

Synonyms:(3,3,3-Trifluoropropyl)dimethylsilylchloride;3,3,3-Trifluoropropyldimethylchlorosilane;Chlorodimethyl(3,3,3-trifluoropropyl)silane;

Chemical Property of CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE

Chemical Property:

• Appearance/Colour: colorless, extremely toxic gas with corruption fish smell
• Refractive Index: n20/D 1.378(lit.)
• Boiling Point: 125.9 °C at 760 mmHg
• Flash Point: 29.9 °C
• PSA: 0.00000
• Density: 1.092g/cm³
• LogP: 3.38270
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 190.0192390
• Heavy Atom Count: 10
• Complexity: 110

Purity/Quality:

99% ^*data from raw suppliers

(3,3,3-Trifluoropropyl)dimethylchlorosilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): FC
• Hazard Codes: F,C
• Statements: 11-34
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: C[Si](C)(CCC(F)(F)F)Cl
• Use Description: CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE is a chemical compound with various applications in different fields. In the field of materials science and surface modification, it serves as a versatile silane coupling agent for enhancing adhesion between organic polymers and inorganic surfaces. Its role is pivotal in the formulation of coatings, adhesives, and sealants, as it improves the compatibility and bonding strength of materials like plastics, rubber, and glass, contributing to the production of durable composite materials. Additionally, in the semiconductor and electronics industry, this compound can be employed in the fabrication of advanced microelectronic devices, where it aids in the formation of hydrophobic and chemically stable surface layers. Its multifaceted utility underscores its significance in advancing materials technology, electronics manufacturing, and industrial applications, where it plays a crucial role in improving material properties, adhesion, and surface treatments.

Technology Process of CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE

There total 6 articles about CHLORODIMETHYL-3,3,3-TRIFLUOROPROPYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dimethylmonochlorosilane (1066-35-9) + 1,1,1-trifluoropropylene (677-21-4) → chlorodimethyl-3,3,3-trifluoropropylsilane (1481-41-0)

Guidance literature:

RhCl(PPh₃)3; at 120 ℃; for 12h;

DOI:10.1016/S0022-328X(00)99483-X

Reference yield:

chloro-trimethyl-silane (75-77-4) + Ethoxy-dimethyl-<3,3,3-trifluor-propyl>-silan (650-29-3) → ethyl trimethylsilyl ether (1825-62-3) + chlorodimethyl-3,3,3-trifluoropropylsilane (1481-41-0)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; In toluene; at 20 ℃; Equilibrium constant; Thermodynamic data; ΔG;

Reference yield:

methyl(3,3,3-trifluoropropyl)dichlorosilane (675-62-7) + dimethylaluminum chloride (1184-58-3) → chlorodimethyl-3,3,3-trifluoropropylsilane (1481-41-0)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); DavePhos; In 1,4-dioxane; hexane; at 120 ℃; for 18h;

DOI:10.1021/acs.orglett.0c04175

upstream raw materials:

dimethylmonochlorosilane

1,1,1-trifluoropropylene

3,3,3-trifluoropropyltrichlorosilane

methyllithium

Downstream raw materials:

1,3-bis(3,3,3-trifluoropropyl)-1,1,3,3-tetramethyldisilazane

4-bromo{dimethyl(3,3,3-trifluoropropyl)silyl}benzene

1,1,2,2-Tetraphenyl-1,2-(dimethyl-3,3,3-trifluoropropylsiloxy)ethane

chloro-trimethyl-silane

Refernces

• 1、 Naganawa, Yuki,Nakajima, Yumiko,Sakamoto, Kei. "A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes". supporting information. p. 601 - 606. Retrieved 2021/01/13.
• 2、 Ojima, Iwao,Fuchikami, Takamasa,Yatabe, Momoko. "THE REACTIONS OF HYDROSILANES WITH TRIFLUOROPROPENE AND PENTAFLUOROSTYRENE CATALYZED BY RUTHENIUM, RHODIUM AND PALLADIUM COMPLEXES". . p. 335 - 346. Retrieved 2007/10/02.