677-21-4Relevant articles and documents
Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt3)3] (E=H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps
Braun, Thomas,Talavera, Maria
supporting information, p. 11926 - 11934 (2021/07/06)
The reaction of the rhodium(I) complexes [Rh(E)(PEt3)3] (E=GePh3 (1), H (6), F (7)) with 1,1,3,3,3-pentafluoropropene afforded the defluorinative germylation products Z/E-2-(triphenylgermyl)-1,3,3,3-tetrafluoropropene and
COMPOSITIONS AND METHODS FOR AN INTEGRATED 2,3,3,3-TETRAFLUOROPROPENE MANUFACTURING PROCESS
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Page/Page column 16; 17, (2020/02/06)
A method of synthesizing 3,3,3-trifluoropropene including contacting 1,3,3,3-tetrachloropropane, in the vapor phase, at a temperature sufficient to effect dehydrochlorination to form 1,1,3-trichloro-1-propene. The 1,1,3-trichloro-1-propene is isolated and subsequently contacted, in the vapor phase, with hydrogen fluoride in the presence of a fluorination catalyst at a temperature sufficient to effect formation of 3,3,3-trifluoropropene.
METHOD FOR PRODUCING 2-CHLORO-3,3,3-TRIFLUOROPROPENE
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Paragraph 0027, (2019/02/13)
The invention relates to a method for producing 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) from at least one compound A selected from the group consisting of halopropane of formulae CX3CHClCH2X or CX3CFClCH3, or halopropenes of formula CQX2CCNCH2 and CX2═CClCH2X where X independently represents a fluorine or chlorine atom, characterised in that it comprises bringing said at least one compound A into contact with HF in a gaseous phase in the presence of a fluorination catalyst AlF3 or fluorine-bearing alumina in order to form a gaseous flow B comprising 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) et 3,3,3-trifluoropropene (HFO-1243zf).