CID 9794785

Base Information

• Chemical Name: CID 9794785
• CAS No.: 994-31-0
• Molecular Formula: C6H15 Cl Sn
• Molecular Weight: 241.348
• Hs Code.: 2931900090
• Mol file: 994-31-0.mol

Synonyms:SCHEMBL149703

Chemical Property of CID 9794785

Chemical Property:

• Vapor Pressure: 1.94mmHg at 25°C
• Melting Point: 50.15℃
• Refractive Index: 1.508 (589.3 nm 20℃)
• Boiling Point: 170.5°Cat760mmHg
• Flash Point: 56.9°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.23040
• Sensitive.: Moisture Sensitive
• Water Solubility.: Hydrolyzes in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 241.988431
• Heavy Atom Count: 8
• Complexity: 25.7

Purity/Quality:

99%, ^*data from raw suppliers

Triethyltin chloride, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
• Statements: 23/24/25-34-50/53
• Safety Statements: 23-28-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Sn+](CC)CC.[Cl-]
• Uses: It is used in the synthesis of some tin alkyls and also in the preparation of organolithium compounds by the transmetalation reaction.

Technology Process of CID 9794785

There total 188 articles about CID 9794785 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

chlorodimethoxyborane (868-81-5) + <β-Methyl-allyl>-triethyl-zinn (74348-94-0) → Trimethyl borate (121-43-7,63156-11-6) + methallyl-dimethoxyborane (54857-24-8) + dimethallylmethoxyborane (74349-03-4) + chlorotriethylstannane (994-31-0)

Guidance literature:

In dichloromethane; (N2); into soln. of B compd. was dropped soln. of Sn compd. within 20 min at -10°C; mixt. was sepd. by fractionated distn. in vac., yielding mixt. of B compds. and sepd. Et3SnCl;

DOI:10.1016/S0022-328X(00)93424-7

Reference yield: 80.0%

triethylaluminum (97-93-8) + tin(IV) chloride (7646-78-8) → chlorotriethylstannane (994-31-0) + tetraethyltin (597-64-8)

Guidance literature:

In diethyl ether; toluene; K. Ziegler and W. P. Neumann, DBP 1 157 617 (1959/63); to stirred soln.of AlEt3 in toluene dropwise added SnCl4 and then Et2O at -25 °C, warmed to room temp., heated for 2 h at 80 °; cooled to -50 °C, added HCl, org. layer washed with Et2O, dried over Na2SO4, distd. in vac.;

DOI:10.1016/0022-328X(82)80003-X

Reference yield: 60.0%

vanadium(V) oxychloride (7727-18-6) + triethylstannane (997-50-2) → vanadium(III) oxide chloride + chlorotriethylstannane (994-31-0) + hydrogen (1333-74-0)

Guidance literature:

In neat (no solvent); heating reagents;;

DOI:10.1021/ja01559a022 DOI:10.1021/ja01575a023

upstream raw materials:

O,O-dimethylphosphorylsulfenyl chloride

tetraethyltin

triethyltin iodide

benzyl chloride

Downstream raw materials:

triethylmethoxystannane

Triethyl-(tert-butylperoxy)-stannan

tetramethylstannane

(C₂H₅)3SnSn(C₆H₅)3

Refernces

• 1、 Cullen, W. R.,Styan, G. E.. "". . p. 633 - 644. Retrieved 1966.
• 2、 Zemlyansky, Nikolay N.,Borisova, Irina V.,Kuznetsova, Marianna G.,Khrustalev, Victor N.,Ustynyuk, Yuri A.,Nechaev, Mikhael S.,Lunin, Valery V.,Barrau, Jacques,Rima, Ghassoub. "New stable germylenes, stannylenes, and related compounds. 1. Stable germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge, Sn) with intramolecular coordination metal-nitrogen bonds. Synthesis and structure". . p. 1675 - 1681. Retrieved 2008/10/08.