DIETHYLALUMINUM CYANIDE SOLUTION

Base Information

• Chemical Name: DIETHYLALUMINUM CYANIDE SOLUTION
• CAS No.: 5804-85-3
• Molecular Formula: C5H10 Al N
• Molecular Weight: 111.123
• Mol file: 5804-85-3.mol

Synonyms:Aluminum,(cyano-C)diethyl-; Aluminum, cyanodiethyl- (7CI,8CI); Cyanodiethylalane;Cyanodiethylaluminum; Diethylaluminum cyanide

Chemical Property of DIETHYLALUMINUM CYANIDE SOLUTION

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 2.03508

Purity/Quality:

98%Min ^*data from raw suppliers

Diethylaluminum cyanide solution 1.0M in toluene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T+,N
• Hazard Codes: F,T+,N
• Statements: 11-26/27/28-32-38-48/20-50/53-63-65-67
• Safety Statements: 36/37-45-60-61-62-28-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1

Technology Process of DIETHYLALUMINUM CYANIDE SOLUTION

There total 1 articles about DIETHYLALUMINUM CYANIDE SOLUTION which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ diethylaluminium cyanide (5804-85-3)

Guidance literature:

DOI:10.1016/S0022-328X(00)87664-0 DOI:10.1039/j19700002675 DOI:10.1016/S0040-4039(00)76271-X DOI:10.1021/ja00768a038

Reference yield: 96.0%

3,5,5-Trimethylcyclohex-2-en-1-one (78-59-1) + diethylaluminium cyanide (5804-85-3) → isophoronenitrile (7027-11-4)

Guidance literature:

In hexane; toluene; at 15 - 20 ℃; for 5h;

Reference yield: 85.0%

isoquinoline (119-65-3) + diethylaluminium cyanide (5804-85-3) + benzoyl chloride (98-88-4) → 2-benzoyl-1-cyano-1,2-dihydroisoquinoline (844-25-7,55839-33-3)

Guidance literature:

In dichloromethane; toluene; Product distribution; various ratios of reactants and reaction times; other heterocyclic bases and acid halides;

Downstream raw materials:

3-trimethylsiloxy-2-cyclohexene-1-carbonitrile

1,5,5-Trimethyl-3-trimethylsilanyloxy-cyclohex-2-enecarbonitrile

6,6-Dimethyl-3-trimethylsilanyloxy-cyclohex-2-enecarbonitrile

3-cyano-2-cyclohexenone