(Z)-Tetradec-7-enal

Base Information

• Chemical Name: (Z)-Tetradec-7-enal
• CAS No.: 65128-96-3
• Molecular Formula: C14H26O
• Molecular Weight: 210.36
• Hs Code.: 2912190090
• European Community (EC) Number: 265-493-9
• UNII: 6Y4KG01SAB
• DSSTox Substance ID: DTXSID401019769
• Nikkaji Number: J750A
• Metabolomics Workbench ID: 3573
• Mol file: 65128-96-3.mol

Synonyms:(Z)-Tetradec-7-enal;Z-7-Tetradecenal;65128-96-3;(z)-7-tetradecenal;7Z-Tetradecenal;7-Tetradecenal, (Z)-;CIS-7-TETRADECENAL;7-Tetradecenal, (7Z)-;(7Z)-7-Tetradecenal;UNII-6Y4KG01SAB;6Y4KG01SAB;EINECS 265-493-9;AI3-35951;(7Z)-tetradec-7-enal;(7Z)-7-Tetradecenal #;SCHEMBL500026;TETRADECENAL, (Z)-7-;AVHNDAZRNRAYTP-FPLPWBNLSA-N;CHEBI:179484;DTXSID401019769;LMFA06000179;Q27265704;Z-7-TETRADECENAL PHEROMONE FOR PLUTELLA XYLOSTELLA AND PRAYS CITRI

Chemical Property of (Z)-Tetradec-7-enal

Chemical Property:

• Appearance/Colour: colorless to pale yellow liquid
• Vapor Pressure: 0.00135mmHg at 25°C
• Refractive Index: 1.448
• Boiling Point: 297.4 °C at 760 mmHg
• Flash Point: 137.9 °C
• PSA: 17.07000
• Density: 0.839 g/cm³
• LogP: 4.66240
• Storage Temp.: -20°C
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 210.198365449
• Heavy Atom Count: 15
• Complexity: 149

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-7-Tetradecenal ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC=CCCCCCC=O
• Isomeric SMILES: CCCCCC/C=C\CCCCCC=O

Technology Process of (Z)-Tetradec-7-enal

There total 11 articles about (Z)-Tetradec-7-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

cis-7,8-epoxy-14(Z)-heneicosene (83807-44-7,83860-43-9) → (Z)-7-tetradecenal (65128-96-3)

Guidance literature:

With periodic acid; In diethyl ether; at 0 ℃; for 1.5h;

DOI:10.1016/0040-4020(82)80148-8

Reference yield:

(Z)-tetradec-7-en-1-ol (40642-43-1) → (Z)-7-tetradecenal (65128-96-3)

Guidance literature:

With pyridium chlorochromate; In dichloromethane; at 20 ℃; for 3h; Yield given;

DOI:10.1021/jo00324a035

Reference yield:

7-tetradecyne-1-ol (37011-94-2) → (Z)-7-tetradecenal (65128-96-3)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1021/jo00374a005

upstream raw materials:

7-tetradecyne-1-ol

(Z)-tetradec-7-en-1-ol

cis-7,8-epoxy-14(Z)-heneicosene

2-(tetradec-7-yn-1-yloxy)tetrahydro-2H-pyran

Downstream raw materials:

(Z)-tetradec-7-enoic acid

2-(4-methoxybenzyloxy)ethyl 2-deoxy-4,6-O-isopropylidene-3-O-[(R)-3-[(Z)-tetradec-7-enyloxy]tetradecyl]-2-trifluoroacetamido-α-D-glycopyranoside

2-(4-methoxybenzyloxy)ethyl 2-deoxy-2-(2,2-difluorotetradecanamido)-4,6-O-isopropylidene-3-O-[(R)-3-[(Z)-tetradec-7-enyloxy]tetradecyl]-α-D-glycopyranoside

3-oxo-(Z)-9-hexadecenal

Refernces

• 1、 Nakamura, Tsuyoshi,Watanabe, Yukiko,Shiozaki, Masao,Kanai, Saori,Kurakata, Shin-ichi. "Synthesis of carboxymethyl GLA-60 ether derivatives containing an olefin in their chains and their LPS-antagonistic activities". . p. 1011 - 1022. Retrieved 2007/10/03.
• 2、 Brown, Herbert C.,Basavaiah, D.,Bhat, N. G.. "Vinylic Organoboranes. 4. A General, One-Pot Synthesis of 6- and 7-Alkyn-1-ols via Boracyclanes. Influence of Steric Effects in the Iodination of Lithium Alkynyl "Ate" Complexes of Dialkylborinates". . p. 4518 - 4521. Retrieved 2007/10/02.