HEXAAMMINERUTHENIUM(III) CHLORIDE

Base Information

• Chemical Name: HEXAAMMINERUTHENIUM(III) CHLORIDE
• CAS No.: 14282-91-8
• Molecular Formula: 3Cl*H₁₈N₆Ru
• Molecular Weight: 309.612
• Hs Code.: 28439000
• Mol file: 14282-91-8.mol

Synonyms:Hexaamminerutheniumtrichloride (6CI,7CI);Ruthenium(3+), hexaammine-, trichloride (8CI);Ruthenium(3+),hexaammine-, trichloride, (OC-6-11)- (9CI);Hexaamineruthenium chloride;Hexaammineruthenium(3+) trichloride;Hexaammineruthenium(III) chloride;Hexaammineruthenium(III) trichloride;Hexaamminetrichlororuthenium;NSC 172783;RuHex chloride;

Chemical Property of HEXAAMMINERUTHENIUM(III) CHLORIDE

Chemical Property:

• Appearance/Colour: yellow crystalline powder
• Vapor Pressure: 5990mmHg at 25°C
• PSA: 19.44000
• LogP: -7.04460
• Storage Temp.: Refrigerator (+4°C)
• Water Solubility.: Very soluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hexaammineruthenium(III)Trichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Hexaamineruthenium(III) Chloride as an Electron Mediator for GlucoseDetection Glucose monitoring systems use hexaammineruthenium(III) chloride as an electron mediator. In one commercial blood glucose monitoring system, β-D-glucose reacts with GOD and hexaammineruthenium (III) chloride in the test strip, generating β-D-glucono-lactone and hexaammineruthenium (II) chloride. The amount of hexaammineruthenium (II) chloride that is produced is directly proportional to the amount of glucose in the blood sample. Oxidation of the hexaammineruthenium(II) chloride back to hexaammineruthenium (III) chloride then generates an electric current. The meter is used to convert the current into the value of the glucose concentration.In another system reported in the literature, the thermostable FADGDH glucose-dehydrogenase complex, rather than GDH, was used as the enzyme and deposited’ along with hexaammineruthenium (III) chloride, onto a screen-printed carbon electrode (SPCE) (Ref 2). The sensor was shown to measure the whole-blood glucose level within 1 sec using a 150-nL whole-blood sample with both high precision and reproducibility. Importantly, the sensor reading was stable for more than 60 days, even at 70 °C.In these systems, the hexaammineruthenium (III) chloride must be of consistent purity and quality to ensure consistent and accurate test results.Reactions:β-D-glucose + Hexammineruthenium(III) chloride + GOD → D-Glucono-δ-Lactone + Hexammineruthenium (II) chlorideHexammineruthenium(II) chloride →Hexammineruthenium(III) chloride + ehttps://www.strem.com Hexaammineruthenium(III) chloride can be used to synthesize chloropentaammineruthenium(III) chloride.

Technology Process of HEXAAMMINERUTHENIUM(III) CHLORIDE

There total 24 articles about HEXAAMMINERUTHENIUM(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

hydrazine hydrate (79785-97-0) + ruthenium(III) chloride trihydrate → hexammine ruthenium(III) chloride (14282-91-8)

Guidance literature:

In water; for 2h; Reflux;

DOI:10.1007/s10562-021-03609-5

Reference yield:

cis-{Ru(HSO3)2(NH3)4} (12437-00-2,25461-57-8,25535-01-7,34797-78-9,67068-53-5) → hexammine ruthenium(III) chloride (14282-91-8) + triamminetrichlororuthenium (III) (173401-46-2,26040-32-4,58240-55-4) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) + ammonium chloride + ruthenium (7440-18-8)

Guidance literature:

With hydrogenchloride; In not given; byproducts: H2O; react. with boiling HCl;;

Reference yield:

hexaammineruthenium(II) chloride (19052-44-9,15305-72-3) + sodium tetrachloroaurate(III) (15189-51-2) → hexammine ruthenium(III) chloride (14282-91-8) + gold (7440-57-5,457905-15-6) + sodium chloride (7647-14-5)

Guidance literature:

In not given; react. with an excess of Na(AuCl4);;

upstream raw materials:

hydrogenchloride

hexaammineruthenium(II) chloride

sulfur dioxide

sodium tetrachloroaurate(III)

Refernces

• 1、 Bakac, Andreja,Butkovi?, Vjera,Espenson, James H.,Marcec, Radovan,Orhanovi?, Matko. "Mechanism of electron transfer to pentaammine(pyridine)cobalt(III) complexes by aliphatic radicals, hexaaquovanadium(II), and hexaamimneruthenium(II) ions". . p. 341 - 345. Retrieved 2008/10/08.