2,2,4-Trimethyl-4-nitropentane

Base Information

• Chemical Name: 2,2,4-Trimethyl-4-nitropentane
• CAS No.: 5342-78-9
• Molecular Formula: C8H17 N O2
• Molecular Weight: 159.228
• Hs Code.: 2904209090
• Mol file: 5342-78-9.mol

Synonyms:2,2,4-Trimethyl-4-nitropentane;2,4,4-Trimethyl-2-nitropentane; 2-Nitro-2,4,4-trimethylpentane;4-Nitro-2,2,4-trimethylpentane; NSC 3658

Chemical Property of 2,2,4-Trimethyl-4-nitropentane

Chemical Property:

• Vapor Pressure: 0.283mmHg at 25°C
• Boiling Point: 203.1°Cat760mmHg
• Flash Point: 61.4°C
• PSA: 45.82000
• Density: 0.917g/cm³
• LogP: 3.00110

Purity/Quality:

98%min ^*data from raw suppliers

2,2,4-TRIMETHYL-4-NITROPENTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2,4-Trimethyl-4-nitropentane

There total 3 articles about 2,2,4-Trimethyl-4-nitropentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,4-trimethylpentane (540-84-1) + nitric acid (7697-37-2,78989-43-2) → 4,4-dimethyl-pentan-2-one (590-50-1) + 2,2,4-trimethylpentanone (5857-36-3) + 2,2,4-trimethyl-3-nitro-pentane (90227-39-7) + 2,2,4-trimethyl-4-nitro-pentane (5342-78-9)

Guidance literature:

at 145 ℃; Prod_.5:Pivalinsaeure; Prod_.6:3,3-Dimethyl-buttersaeure; Prod_.7:2,2-Dimethyl-bernsteinsaeure;

Reference yield:

2-nitropropane (79-46-9) + 1-neopentyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate (81128-05-4) → 2,2,4-trimethyl-4-nitro-pentane (5342-78-9) + 2,4,6-triphenylpyridine (580-35-8)

Guidance literature:

With sodium hydride; Yield given. Multistep reaction; 1.) CH₃OH, 2.) DMSO, 80 deg C, 2 h;

DOI:10.1021/ja00339a016

Reference yield:

sodium 2-nitropropane (24163-39-1) + 1-neopentyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate (81128-05-4) → 2,2,4-trimethyl-4-nitro-pentane (5342-78-9) + 2,4,6-triphenylpyridine (580-35-8)

Guidance literature:

In dimethyl sulfoxide; at 25 ℃; for 2h; Rate constant; Kinetics;

DOI:10.1021/ja00339a016

upstream raw materials:

2-nitropropane

1-neopentyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate

sodium 2-nitropropane

2,2,4-trimethylpentane

Downstream raw materials:

2,2,4-trimethylpentane

2,4,4-trimethyl-1-pentene

2,4,4-trimethylpent-2-ene

tert-octyl mercaptan

Refernces