Benzenesulfonic acid p-nitrophenyl ester

Base Information

• Chemical Name: Benzenesulfonic acid p-nitrophenyl ester
• CAS No.: 3313-84-6
• Molecular Formula: C12H9 N O5 S
• Molecular Weight: 279.273
• Mol file: 3313-84-6.mol

Synonyms:Benzenesulfonicacid, p-nitrophenyl ester (6CI,7CI,8CI); NSC 406665; p-Nitrophenylbenzenesulfonate

Chemical Property of Benzenesulfonic acid p-nitrophenyl ester

Chemical Property:

• Vapor Pressure: 2.37E-08mmHg at 25°C
• Boiling Point: 464.2°Cat760mmHg
• Flash Point: 234.5°C
• PSA: 97.57000
• Density: 1.432g/cm³
• LogP: 3.96650

Purity/Quality:

99%min ^*data from raw suppliers

BENZENESULFONIC ACID 4-NITRO-PHENYL ESTER AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenesulfonic acid p-nitrophenyl ester

There total 5 articles about Benzenesulfonic acid p-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tert-butyldimethyl(4-nitrophenoxy)silane (117635-44-6) + N-fluorobis(benzenesulfon)imide (133745-75-2) → 4-nitrophenyl benzenesulfonate (3313-84-6)

Guidance literature:

N-fluorobis(benzenesulfon)imide; With potassium fluoride; In N,N-dimethyl-formamide; at 20 ℃; for 0.0833333h;

tert-butyldimethyl(4-nitrophenoxy)silane; In N,N-dimethyl-formamide; at 20 ℃; for 1h;

DOI:10.1016/j.tetlet.2020.151660

Reference yield: 87.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + benzenesulfonyl chloride (98-09-9) → 4-nitrophenyl benzenesulfonate (3313-84-6)

Guidance literature:

With triethylamine; In dichloromethane; for 1h; Cooling with ice;

DOI:10.1016/j.bmcl.2021.128290

Reference yield: 85.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + sodium benzenesulfonate (873-55-2) → 4-nitrophenyl benzenesulfonate (3313-84-6)

Guidance literature:

With sodium iodide; In acetonitrile; at 20 ℃; for 4h; Electrochemical reaction; Green chemistry;

DOI:10.1016/j.tet.2021.132444

upstream raw materials:

phenyl benzenesulfonate

4-nitro-phenol

benzenesulfonyl chloride

tert-butyldimethyl(4-nitrophenoxy)silane

Downstream raw materials:

4-nitro-phenol

phenyl benzenesulfonate

N-(2-chlorobenzyl)-4-methybenzenesulfonamide

benzenesulfonic acid

Refernces

• 1、 Ma, Jinfeng,Xu, Pan,Zhong, Zijian,Zhou, Aihua. "Electrochemical cross-coupling reactions of sodium arenesulfinates with thiophenols and phenols". supporting information. . Retrieved 2021/10/26.
• 2、 Dond, Bharat D.,Thore, Shivaji N.. "NFSI/KF mediated mild and chemoselective interconversion of aryl TBDMS ethers to their benzene sulfonate". supporting information. . Retrieved 2020/02/06.