Phosphorodiamidothioic chloride, tetramethyl-

Base Information

• Chemical Name: Phosphorodiamidothioic chloride, tetramethyl-
• CAS No.: 3732-81-8
• Molecular Formula: C4H12ClN2PS
• Molecular Weight: 186.645
• DSSTox Substance ID: DTXSID50190768
• Nikkaji Number: J113.755G
• Wikidata: Q83063175
• Mol file: 3732-81-8.mol

Synonyms:Phosphorodiamidothioic chloride, tetramethyl-;3732-81-8;Tetramethyldiamidothiophosphoryl chloride;Bis(dimethylamino)chlorophosphine sulfide;N,N,N',N'-Tetramethylphosphorodiamidothioic chloride;SCHEMBL6293143;DTXSID50190768;CDAZTLZRVPHQHS-UHFFFAOYSA-N;Tetramethylphosphorodiamidothioic chloride;Bis(dimethylamino)phosphinothioic chloride

Chemical Property of Phosphorodiamidothioic chloride, tetramethyl-

Chemical Property:

• Melting Point: 21.85°C
• Boiling Point: 201°Cat760mmHg
• Flash Point: 75.4°C
• PSA: 48.38000
• Density: 1.224g/cm³
• LogP: 2.22350
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 186.0147343
• Heavy Atom Count: 9
• Complexity: 125

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)P(=S)(N(C)C)Cl

Technology Process of Phosphorodiamidothioic chloride, tetramethyl-

There total 1 articles about Phosphorodiamidothioic chloride, tetramethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(N,N-dimethylamino)chlorophosphine (3348-44-5) → N,N,N',N'-Tetramethylphosphorodiamidic chloride (1605-65-8) + N,N,N',N'-tetramethylphosphorodiamidothioic chloride (3732-81-8)

Guidance literature:

With sulfur dioxide; at 0 ℃; for 1h; Yield given. Yields of byproduct given;

Reference yield: 56.0%

m-hydroxyphenyl(diphenyl)phosphine sulfide (32341-36-9) + N,N,N',N'-tetramethylphosphorodiamidothioic chloride (3732-81-8) → (N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester (1198151-79-9)

Guidance literature:

With triethylamine; at 115 - 120 ℃; for 3h;

DOI:10.1039/b907644a

upstream raw materials:

bis(N,N-dimethylamino)chlorophosphine

Downstream raw materials:

(N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester

Refernces