1,10-Dibromodecane

Base Information

• Chemical Name: 1,10-Dibromodecane
• CAS No.: 4101-68-2
• Molecular Formula: C10H20Br2
• Molecular Weight: 300.077
• Hs Code.: 29049090
• European Community (EC) Number: 223-871-0
• NSC Number: 6086
• DSSTox Substance ID: DTXSID4063298
• Nikkaji Number: J34.959C
• Wikidata: Q57985172
• Mol file: 4101-68-2.mol

Synonyms:1,10-Dibromodecane;4101-68-2;1,10-Dibromodecan;Decamethylene dibromide;Decane, 1,10-dibromo-;1,10-dibromo-decane;NSC 6086;MFCD00000222;1,10-dibromo-decan;EINECS 223-871-0;AI3-11007;1,10-Decamethylene Bromide;1,10-Decamethylene Dibromide;C10H20Br2;a,w-Dibromodecane;NSC6086;1,10-dibromdecane;1,10 dibromodecane;Decane,10-dibromo-;1,10-Dibromodecane-;SCHEMBL51802;1,10-Dibromodecane, 97%;DTXSID4063298;C10-H20-Br2;AMY11211;NSC-6086;AKOS009157230;CS-W009956;BP-21400;SY012704;D0179;FT-0607698;EN300-48595;A26523;F11241;F0001-1158

Chemical Property of 1,10-Dibromodecane

Chemical Property:

• Appearance/Colour: beige to brown crystalline low melting mass
• Vapor Pressure: 0.00233mmHg at 25°C
• Melting Point: 25-27 °C(lit.)
• Refractive Index: n20/D 1.4912(lit.)
• Boiling Point: 297.9 °C at 760 mmHg
• Flash Point: 153.4 °C
• PSA: 0.00000
• Density: 1.364 g/cm³
• LogP: 4.89700
• Storage Temp.: 2-8°C
• Water Solubility.: insoluble
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 299.99113
• Heavy Atom Count: 12
• Complexity: 64.2

Purity/Quality:

99% ^*data from raw suppliers

1,10-Dibromodecane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C, Xi
• Hazard Codes: C,Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 22-24/25-36-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Unsaturated
• Canonical SMILES: C(CCCCCBr)CCCCBr
• Uses: 1,10-Dibromodecane is used as an alkylating agent and as synthetic organic intermediate.

Technology Process of 1,10-Dibromodecane

There total 20 articles about 1,10-Dibromodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,10-decadiene (1647-16-1) → 1,10-dibromodecane (4101-68-2)

Guidance literature:

With 2,2,4-trimethylpentane; tetradecafluorohexane; bromine; at 20 ℃; for 2h; Irradiation;

DOI:10.1055/s-0030-1258482

Reference yield: 91.0%

1,10-Decanediol (112-47-0) → 1,10-dibromodecane (4101-68-2)

Guidance literature:

With hydrogen bromide; In octane; water; at 145 ℃; for 7h; Dean-Stark;

DOI:10.1016/j.tetlet.2014.11.132

Reference yield: 90.0%

C7H13BrO3 (1373139-23-1) → 1,10-dibromodecane (4101-68-2)

Guidance literature:

With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane; In tetrahydrofuran; for 3h; Inert atmosphere;

DOI:10.1021/jo300344a

upstream raw materials:

1,10-Decanediol

6-bromohexanoic acid

sebacic acid mono methyl ester

1,5-dibromo-pentane

Downstream raw materials:

decamethylene bis(pyridinium bromide)

4,4'-dimethyl-1,1'-decanediyl-bis-pyridinium; dibromide

1,10-bis(isoquinolinium)decane dibromide

3,3'-dimethyl-2,2'-decanediyl-bis-isoquinolinium; dibromide

Refernces

• 1、 Listunov, Dymytrii,Fabing, Isabelle,Saffon-Merceron, Nathalie,Gaspard, Hafida,Volovenko, Yulian,Maraval, Valérie,Chauvin, Remi,Génisson, Yves. "Asymmetric synthesis and biological evaluation of natural or bioinspired cytotoxic C 2-symmetrical lipids with two terminal chiral alkynylcarbinol pharmacophores". . p. 5386 - 5394. Retrieved 2015.
• 2、 Maiti, Kajari,Mitra, Debolina,Mitra, Rajendra N.,Panda, Amiya K.,Das, Prasanta K.,Rakshit, Animesh K.,Moulik, Satya P.. "Self-aggregation of synthesized novel bolaforms and their mixtures with sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB) in aqueous medium". . p. 7499 - 7508. Retrieved 2010.
• 3、 Tan, Xinqiang,Song, Tao,Wang, Zhentao,Chen, He,Cui, Lei,Li, Chaozhong. "Silver-Catalyzed Decarboxylative Bromination of Aliphatic Carboxylic Acids". supporting information. p. 1634 - 1637. Retrieved 2017/04/11.
• 4、 Mekala, Shekar,Hahn, Roger C.. "Process intensification-assisted conversion of α,ω-alkanediols to dibromides". supporting information. p. 630 - 632. Retrieved 2015/03/03.