(Chloromethyl)dimethylsilane

Base Information

• Chemical Name: (Chloromethyl)dimethylsilane
• CAS No.: 3144-74-9
• Molecular Formula: C3H9ClSi
• Molecular Weight: 108.643
• Hs Code.: 2931900090
• European Community (EC) Number: 221-556-2
• NSC Number: 96776
• UNII: 53NF3P6VJM
• DSSTox Substance ID: DTXSID60883957
• Mol file: 3144-74-9.mol

Synonyms:(Chloromethyl)dimethylsilane;3144-74-9;Dimethyl(chloromethyl)silane;CHLOROMETHYLDIMETHYLSILANE;Silane, (chloromethyl)dimethyl-;Chloromethyl(dimethyl)silane;53NF3P6VJM;EINECS 221-556-2;NSC 96776;NSC-96776;NSC96776;ClCH2SiH(CH3)2;UNII-53NF3P6VJM;Silane,(chloromethyl)dimethyl-;SCHEMBL1324976;DTXSID60883957;MFCD00054835;AKOS006377801;FT-0694965

Chemical Property of (Chloromethyl)dimethylsilane

Chemical Property:

• Melting Point: <0 °C
• Refractive Index: n20/D 1.42(lit.)
• Boiling Point: 81.6 °C at 760 mmHg
• Flash Point: 10 °F
• PSA: 0.00000
• Density: 0.894 g/mL at 25 °C(lit.)
• LogP: 1.66940
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 107.0083795
• Heavy Atom Count: 5
• Complexity: 20.9

Purity/Quality:

99% ^*data from raw suppliers

Chloromethyl(dimethyl)silane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11
• Safety Statements: 7-16-29-33

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)CCl

Technology Process of (Chloromethyl)dimethylsilane

There total 2 articles about (Chloromethyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Chloro(chloromethyl)dimethylsilane (1719-57-9) → chloromethyldimethylsilane (3144-74-9)

Guidance literature:

With lithium aluminium tetrahydride; In dibutyl ether; under 0.8 - 3.8 Torr;

Reference yield:

→ chloromethyldimethylsilane (3144-74-9)

Guidance literature:

DOI:10.1021/jo00868a009

Reference yield: 99.0%

chloromethyldimethylsilane (3144-74-9) + C60H60O14Si10 → C72H96Cl4O14Si14

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In toluene; at 40 ℃; for 16h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.0c02515

upstream raw materials:

Chloro(chloromethyl)dimethylsilane

Downstream raw materials:

Jodmethyl-dimethyl-silan

γ-Hydroxypropyl-chlormethyl-dimethyl-silan

(γ-Trimethylsiloxypropyl)-chlormethyl-dimethyl-silan

4-(chloromethyldimethylsilanyl)butan-1-ol

Refernces

• 1、 Steward,O.W.,Pierce,O.R.. "-". . p. 4932 - 4936. Retrieved 1961.
• 2、 Reissmann, Matti,Sch?fer, Andr,Panisch, Robin,Schmidtmann, Marc,Bolte, Michael,Müller, Thomas. "Cyclic silylated onium ions of group 15 elements". . p. 2393 - 2402. Retrieved 2015/03/18.
• 3、 Thibon, Jacques,Latxague, Laurent,Deleris, Gerard. "Synthesis of silicon analogues of acyclonucleotides incorporable in oligonucleotide solid-phase synthesis". . p. 4635 - 4642. Retrieved 2007/10/03.