Diruthenium pentaoxide

Base Information

• Chemical Name: Diruthenium pentaoxide
• CAS No.: 12137-44-9
• Molecular Formula: ORu
• Molecular Weight: 117.069
• Mol file: 12137-44-9.mol

Synonyms:diruthenium pentaoxide

Chemical Property of Diruthenium pentaoxide

Chemical Property:

• PSA: 0.00000
• LogP: -0.59400

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diruthenium pentaoxide

There total 30 articles about Diruthenium pentaoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorotetrakis(dimethylsulfoxide)ruthenium(II) → ruthenium disulfide + ruthenium (II) oxide (12137-44-9) + ruthenium (7440-18-8)

Guidance literature:

In neat (no solvent); heating up to 700°C; TA-DTG;

Reference yield:

tris(2,2'-dipyridyl)ruthenium(II) hexachloroplumbate (115777-63-4) → ruthenium(II) chloride + ruthenium (II) oxide (12137-44-9) + lead(II) oxide + ruthenium (7440-18-8)

Guidance literature:

In solid; byproducts: 2,2'-dipyridyl, chlorine; thermal decomposition up to 1000 K in N2, the heating rate of 10 deg/min: Cl2 (part of it consumed in formn. of chloropyridines), at higher temp. also dipy;

DOI:10.1007/BF01913964

Reference yield:

ruthenium tetroxide (20427-56-9) → ruthenium(IV) oxide + ruthenium(VI) oxide + ruthenium (II) oxide (12137-44-9) + oxygen + ruthenium (7440-18-8)

Guidance literature:

In neat (no solvent, gas phase); byproducts: O2; Irradiation (UV/VIS); irradiation of gaseous RuO4 (1-5 Torr) in a fluorescence cell at 240-320 nm; monitored by UV;

DOI:10.1021/j100369a039

upstream raw materials:

ruthenium

oxygen-18

dioxygen-⁽¹⁶⁾O

ruthenium tetroxide

Refernces

• 1、 Connick, R. E.,Hurley, C. R.. "". . p. 5012 - 5015. Retrieved 1952.
• 2、 Larsen, R. P.,Ross, L. E.. "". . p. 176 - 178. Retrieved 1959.
• 3、 Alibrahim, Khuloud A.,Al-Saif, Foziah A.,Alghamdi,El-Shahawi,Moustafa,Refat, Moamen S.. "Synthesis, spectroscopic, thermal, antimicrobial and electrochemical characterization of some novel Ru(iii), Pt(iv) and Ir(iii) complexes of pipemidic acid". . p. 22515 - 22529. Retrieved 2018.
• 4、 Szychlinski, J.,Lubkowski, J.,Blazejowski, J.,Bujewski, A.. "". . p. 1769 - 1772. Retrieved 1987.
• 5、 Al-Noaimi, Mousa,Warad, Ismail,Abdel-Rahman, Obadah S.,Awwadi, Firas F.,Haddad, Salim F.,Hadda, Taibi B.. "Synthesis, structure, spectroscopic properties, electrochemistry, and DFT correlative studies of trans-[Ru(P-P)2Cl2] complexes". . p. 110 - 119. Retrieved 2013/10/22.