Butyl myristate

Base Information

• Chemical Name: Butyl myristate
• CAS No.: 110-36-1
• Molecular Formula: C18H36 O2
• Molecular Weight: 284.483
• Hs Code.: 2915900090
• European Community (EC) Number: 203-759-8
• NSC Number: 4814
• UNII: O061W4C37H
• DSSTox Substance ID: DTXSID4038716
• Nikkaji Number: J150.309J
• Wikidata: Q27285150
• ChEMBL ID: CHEMBL206900
• Mol file: 110-36-1.mol

Synonyms:BUTYL MYRISTATE;Butyl tetradecanoate;110-36-1;Myristic acid n-butyl ester;Tetradecanoic acid, butyl ester;Bumyr;Butyl n-tetradecanoate;Myristic acid, butyl ester;Wickenol 141;n-Butyl myristate;NSC 4814;EINECS 203-759-8;BRN 1782649;UNII-O061W4C37H;AI3-07958;O061W4C37H;NSC-4814;Butyl=myristate;Crodamol BM;Nikkol BM;n-Butyl tetradecanoate;Myristic Acid Butyl Ester;Butyl myristate, AldrichCPR;SCHEMBL43540;BUTYL MYRISTATE [INCI];CHEMBL206900;DTXSID4038716;NSC4814;Tetradecanoic acid, n-butyl ester;MFCD00015077;AKOS024390872;HY-W099584;BS-23651;LS-148900;CS-0152226;FT-0629054;M0477;D91335;W-109403;Q27285150;(Tetradecanoic acid, butyl ester)

Chemical Property of Butyl myristate

Chemical Property:

• Vapor Pressure: 0.000126mmHg at 25°C
• Melting Point: 6.8°C
• Refractive Index: 1.4380 to 1.4410
• Boiling Point: 334.7°Cat760mmHg
• Flash Point: 158.5°C
• PSA: 26.30000
• Density: 0.864g/cm³
• LogP: 6.03080
• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 16
• Exact Mass: 284.271530387
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

98%, ^*data from raw suppliers

Butyl Myristate >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: R36/38:Irritating to eyes and skin.
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Esters, Other
• Canonical SMILES: CCCCCCCCCCCCCC(=O)OCCCC

Technology Process of Butyl myristate

There total 4 articles about Butyl myristate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

n-tetradecanoic acid (544-63-8) + butan-1-ol (71-36-3) → n-butyl myristate (110-36-1)

Guidance literature:

With cerium(III) trislaurylsulfonate monohydrate; In neat (no solvent); at 80 ℃; for 6h;

DOI:10.1016/j.molcata.2014.04.031

Reference yield: 74.0%

n-tetradecanoic acid (544-63-8) + N-butylamine (109-73-9,85404-21-3) → n-butyl myristate (110-36-1)

Guidance literature:

With sulfuric acid; Heating;

DOI:10.1016/j.bmcl.2006.02.056

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) + 1-tetradecene (1120-36-1) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + 1-undecene (821-95-4) + 1-tridecene (2437-56-1) + 1-pentadecene (13360-61-7) + carbon monoxide (201230-82-2) + butan-1-ol (71-36-3) → butyl undecanoate (10580-24-2) + butyl laurate (106-18-3) + n-butyl tridecanoate (28267-31-4) + n-butyl myristate (110-36-1) + butyl palmitate (111-06-8) + Butyl pentadecanoate (35996-97-5)

Guidance literature:

With pyridine; dicobalt octacarbonyl; at 160 ℃; for 24h; under 60006 - 75007.5 Torr; Conversion of starting material;

upstream raw materials:

n-tetradecanoic acid

butan-1-ol

N-butylamine

1-dodecene

Downstream raw materials:

1-Tetradecanol

sulfuric acid monotetradecyl ester

undecyl alcohol

pentadecanol

Refernces

• 1、 Varyambath, Anuraj,Kim, Mi-Ra,Kim, Il. "Sulfonic acid-functionalized organic knitted porous polyaromatic microspheres as heterogeneous catalysts for biodiesel production". . p. 12745 - 12753. Retrieved 2018/08/04.
• 2、 Qiu, Yunfeng,Sun, Hongnan,Ma, Zhuo,Xia, Wujiong. "Efficient, stable, and reusable Lewis acid-surfactant-combined catalyst: One-pot Biginelli and solvent-free esterification reactions". . p. 76 - 82. Retrieved 2014/06/10.