1-Propanol, 3-(trimethylsilyl)-, carbamate

Base Information

• Chemical Name: 1-Propanol, 3-(trimethylsilyl)-, carbamate
• CAS No.: 3124-35-4
• Molecular Formula: C₇H₁₇NO₂Si
• Molecular Weight: 175.303
• NSC Number: 92692
• DSSTox Substance ID: DTXSID50185159
• Nikkaji Number: J69.785K
• Wikidata: Q83056141
• Mol file: 3124-35-4.mol

Synonyms:3-(trimethylsilyl)propyl carbamate;1-Propanol, 3-(trimethylsilyl)-, carbamate;3124-35-4;3-(Trimethylsilyl)-1-propanol carbamate;Carbamic acid, 3-(trimethylsilyl)propyl ester;BRN 2411130;3-(Trimethylsilyl)propyl ester of carbamic acid;NCIOpen2_001389;DTXSID50185159;NSC92692;NSC 92692;NSC-92692

Chemical Property of 1-Propanol, 3-(trimethylsilyl)-, carbamate

Chemical Property:

• Vapor Pressure: 0.0198mmHg at 25°C
• Boiling Point: 252°Cat760mmHg
• Flash Point: 106.2°C
• Density: 0.937g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 175.102855319
• Heavy Atom Count: 11
• Complexity: 131

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CCCOC(=O)N

Technology Process of 1-Propanol, 3-(trimethylsilyl)-, carbamate

There total 5 articles about 1-Propanol, 3-(trimethylsilyl)-, carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-trimethylsilylpropionic acid (5683-30-7) → Trimethyl-(3-carbamoyloxy-propyl)-silan (3124-35-4)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄

2: (i) Py, (ii) liq. NH₃

With lithium aluminium tetrahydride;

DOI:10.1021/jm00329a012

Reference yield:

3-trimethylsilyl-1-propanol (2917-47-7) + sodium isocyanate (917-61-3) → Trimethyl-(3-carbamoyloxy-propyl)-silan (3124-35-4)

Guidance literature:

With trifluoroacetic acid; In benzene;

Reference yield:

Trimethyl-<3-chlorcarbonyloxy-propyl>-silan (13625-70-2) → Trimethyl-(3-carbamoyloxy-propyl)-silan (3124-35-4)

Guidance literature:

With ammonium hydroxide;

upstream raw materials:

3-trimethylsilyl-1-propanol

sodium isocyanate

Trimethyl-<3-chlorcarbonyloxy-propyl>-silan

phenyl chloroformate

Refernces