3-Dodecen-1-ol, (3Z)-

Base Information

• Chemical Name: 3-Dodecen-1-ol, (3Z)-
• CAS No.: 32451-95-9
• Molecular Formula: C12H24O
• Molecular Weight: 184.322
• Hs Code.: 2905290000
• European Community (EC) Number: 251-057-5
• Mol file: 32451-95-9.mol

Synonyms:3-Dodecen-1-ol, (3Z)-;dodec-3-en-1-ol;32451-95-9;AKOS028109409

Chemical Property of 3-Dodecen-1-ol, (3Z)-

Chemical Property:

• Vapor Pressure: 0.00106mmHg at 25°C
• Refractive Index: 1.456
• Boiling Point: 268.1 °C at 760 mmHg
• PKA: 14.90±0.10(Predicted)
• Flash Point: 97.6 °C
• PSA: 20.23000
• Density: 0.846 g/cm³
• LogP: 3.67560
• Storage Temp.: Amber Vial, Refrigerator, Under inert atmosphere
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 184.182715385
• Heavy Atom Count: 13
• Complexity: 108

Purity/Quality:

98%Min ^*data from raw suppliers

cis-3-Dodecen-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC=CCCO
• Uses: cis-3-Dodecen-1-ol is an intermediate for the synthesis of Z-3-Dodecenyl E-Crotonate, which?can be used to develop insecticides and sex pheromone trap against?Sweetpotato weevil.

Technology Process of 3-Dodecen-1-ol, (3Z)-

There total 23 articles about 3-Dodecen-1-ol, (3Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dodec-3-yn-1-ol (55182-73-5) → (Z)-Dodec-3-en-1-ol (32451-95-9)

Guidance literature:

With hydrogen; P-2 Ni; In ethanol;

Reference yield: 89.0%

2-[((Z)-Dodec-3-enyl)oxy]-tetrahydro-pyran (88841-48-9) → (Z)-Dodec-3-en-1-ol (32451-95-9)

Guidance literature:

With dowex; In methanol; at 45 ℃;

DOI:10.1021/jo00181a023

Reference yield: 73.0%

(Z)-3-Dodecensaeure-ethylester (79837-93-7) → (Z)-Dodec-3-en-1-ol (32451-95-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1002/jlac.198119810920

upstream raw materials:

dodec-3-yn-1-ol

2-[((Z)-Dodec-3-enyl)oxy]-tetrahydro-pyran

(Z)-3-Dodecensaeure-ethylester

1-decyne

Downstream raw materials:

(Z)-3-dodecenoic acid

3-dodecenyltriphenylphosphonium p-toluenesulfonate

methyl (1E,3Z,6Z)-4-(1,3,6-pentadecatrienylthio)benzoate

methyl (1E,3Z,6Z)-3-(1,3,6-pentadecatrienylthio)benzoate

Refernces

• 1、 D’yakonov, Vladimir A.,Makarov, Alexey A.,Dzhemileva, Lilya U.,Ramazanov, Ilfir R.,Makarova, Elina Kh.,Dzhemilev, Usein M.. "Natural trienoic acids as anticancer agents: First stereoselective synthesis, cell cycle analysis, induction of apoptosis, cell signaling and mitochondrial targeting studies". . . Retrieved 2021/04/13.
• 2、 Le, Van-Dung,Le, T. Cam-Huong,Chau, Van-Trung,Le, T. Ngoc-Duyen,Dang, Chi-Hien,Vo, T. To-Nguyen,Nguyen, Trinh Duy,Nguyen, Thanh-Danh. "Palladium nanoparticlesin situsynthesized onCyclea barbatapectin as a heterogeneous catalyst for Heck coupling in water, the reduction of nitrophenols and alkynes". . p. 4746 - 4755. Retrieved 2021/03/22.