CAS No.32451-95-9,(Z)-dodec-3-en-1-ol Suppliers

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Basic Information

Molecular Structure:
CAS No.:	32451-95-9
Name:	(Z)-dodec-3-en-1-ol
Article Data:	18

Formula:	C₁₂H₂₄O
Molecular Weight:	184.322
Synonyms:	3-Dodecen-1-ol,(Z)- (8CI);(Z)-3-Dodecen-1-ol;cis-3-Dodecen-1-ol;
EINECS:	251-057-5
Density:	0.846 g/cm³
Boiling Point:	268.1 °C at 760 mmHg
Flash Point:	97.6 °C
PSA:	20.23000
LogP:	3.67560

Synthetic route

: 55182-73-5
dodec-3-yn-1-ol

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
With hydrogen; P-2 Ni In ethanol	100%
With hydrogen	96%
With quinoline; hydrogen; Lindlar's catalyst In hexane Ambient temperature;	96%

: 88841-48-9
2-[((Z)-Dodec-3-enyl)oxy]-tetrahydro-pyran

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
With dowex In methanol at 45℃;	89%
With toluene-4-sulfonic acid In methanol at 20℃; for 16h;	0.28 g

: 79837-93-7
(Z)-3-Dodecensaeure-ethylester

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether	73%

: 1-benzyloxy-4-fluoro-3-dodecene

A: (E)-4-fluoro-dodec-3-en-1-ol

B: (Z)-4-fluoro-dodec-3-en-1-ol

C: 32451-95-9
(Z)-Dodec-3-en-1-ol

D: 68900-87-8
(E)-3-dodecene-1-ol

Conditions

Conditions	Yield
With ammonia; lithium In ethanol at -78℃; Title compound not separated from byproducts.;

...Expand

: 764-93-2
1-decyne

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) BuLi / 1.) HMPA, hexane, a) RT, 15 min, b) 50 deg C, 0.5 h, 2.) HMPA, hexane, a) RT, 1.5 h, b) 50 deg C, 2 h 2: 91 percent / H2, quinoline / Lindlar catalyst / hexane / 1 h / 10 °C View Scheme
Multi-step reaction with 4 steps 1: 1.) n-BuLi, 2.) HMPA / 1.) THF, -20 deg C, 0.5 h, 2.) THF, -78 deg C, 3 h 2: 84 percent / 2 N HCl / acetone / 6 h 3: 86 percent / NaBH4 4: 100 percent / H2 / P-2 Ni / ethanol View Scheme
Multi-step reaction with 2 steps 1: 1.) n-BuLi / 1.) THF/HMPA 2: H2 / Lindlar cat. / hexane View Scheme

: 111-83-1
1-bromo-octane

sodium-compound of decylmalonic acid diethyl ester: sodium-compound of decylmalonic acid diethyl ester

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) LiNH2, NH3 / 1.) THF, 45 min, 2.) THF, 5 h 2: 96 percent / H2, quinoline / 5percent Pd/CaCO3 / hexane / Ambient temperature View Scheme

: 112-31-2
caprinaldehyde

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: 63 percent / piperidine / xylene / Heating 2: 83 percent / LAH / diethyl ether 3: Br2 / CCl4 4: NaNH2 / CCl4; aq. NH3 / 4 h / -78 °C 5: 100 percent / H2 / P-2 Ni / ethanol View Scheme
Multi-step reaction with 3 steps 1: tetrahydrofuran / 0 - 20 °C 2: hydrogenchloride / benzene 3: 4,4'-di-tert-butylbiphenyl; lithium / tetrahydrofuran / 0 - 20 °C View Scheme

: 4998-72-5
(E)-dodec-3-enoic acid

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 83 percent / LAH / diethyl ether 2: Br2 / CCl4 3: NaNH2 / CCl4; aq. NH3 / 4 h / -78 °C 4: 100 percent / H2 / P-2 Ni / ethanol View Scheme

: 68900-87-8
(E)-3-dodecene-1-ol

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: Br2 / CCl4 2: NaNH2 / CCl4; aq. NH3 / 4 h / -78 °C 3: 100 percent / H2 / P-2 Ni / ethanol View Scheme

: 3,4-Dibromo-dodecan-1-ol

: 32451-95-9
(Z)-Dodec-3-en-1-ol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: NaNH2 / CCl4; aq. NH3 / 4 h / -78 °C 2: 100 percent / H2 / P-2 Ni / ethanol View Scheme

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Specification

The 3-Dodecen-1-ol, (3Z)-, with the CAS registry number 32451-95-9, is also known as (3Z)-Dodec-3-en-1-ol. Its EINECS registry number is 251-057-5. This chemical's molecular formula is C₁₂H₂₄O and molecular weight is 184.32. What's more, its IUPAC name is called (Z)-Dodec-3-en-1-ol.

Physical properties about 3-Dodecen-1-ol, (3Z)- are: (1)ACD/LogP: 4.80; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 1; (4)#H bond donors: 1; (5)#Freely Rotating Bonds: 10; (6)Polar Surface Area: 9.23 Å²; (7)Index of Refraction: 1.456; (8)Molar Refractivity: 59.23 cm³; (9)Molar Volume: 217.7 cm³; (10)Surface Tension: 30.9 dyne/cm; (11)Density: 0.846 g/cm³; (12)Flash Point: 97.6 °C; (13)Enthalpy of Vaporization: 58.77 kJ/mol; (14)Boiling Point: 268.1 °C at 760 mmHg; (15)Vapour Pressure: 0.00106 mmHg at 25 °C.

Preparation of 3-Dodecen-1-ol, (3Z)-: this chemical can be prepared by Dodec-3-yn-1-ol. This reaction needs reagent H₂ and solvent methanol. The yield is 96 %.

3-Dodecen-1-ol, (3Z)- can be prepared by Dodec-3-yn-1-ol.

Uses of 3-Dodecen-1-ol, (3Z)-: it is used to produce other chemicals. For example, it can react with Toluene-4-sulfonyl chloride to get (Z)-3-Dodecenyl p-toluenesulfonate. The reaction occurs with solvent pyridine at temperature of 2-5 °C. The reaction time is 20 hours.

3-Dodecen-1-ol, (3Z)- can react with Toluene-4-sulfonyl chloride to get (Z)-3-Dodecenyl p-toluenesulfonate.

You can still convert the following datas into molecular structure:
(1) SMILES: OCC\C=C/CCCCCCCC
(2) InChI: InChI=1S/C12H24O/c1-2-3-4-5-6-7-8-9-10-11-12-13/h9-10,13H,2-8,11-12H2,1H3/b10-9-
(3) InChIKey: BDGQTWOHKASHQU-KTKRTIGZSA-N