tert-Butyl(iodo)dimethylsilane

Base Information

• Chemical Name: tert-Butyl(iodo)dimethylsilane
• CAS No.: 72726-45-5
• Molecular Formula: C6H15ISi
• Molecular Weight: 242.175
• DSSTox Substance ID: DTXSID30502860
• Nikkaji Number: J812.560K
• Wikidata: Q63398271
• Mol file: 72726-45-5.mol

Synonyms:tert-Butyl(iodo)dimethylsilane;72726-45-5;tert-butyl-iodo-dimethylsilane;Silane, (1,1-dimethylethyl)iododimethyl-;t-butyldimethylsilyl iodide;SCHEMBL2916861;DTXSID30502860;ODGTVVCTZIKYTG-UHFFFAOYSA-N;TERT-BUTYLIODODIMETHYLSILANE;TERT-BUTYLDIMETHYLSILYL IODIDE;Q63398271

Chemical Property of tert-Butyl(iodo)dimethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 3.42660
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 241.99877
• Heavy Atom Count: 8
• Complexity: 81

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)[Si](C)(C)I

Technology Process of tert-Butyl(iodo)dimethylsilane

There total 4 articles about tert-Butyl(iodo)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tert-butyldimethylsilane (29681-57-0) → tert-butyldimethylsilyl iodide (72726-45-5)

Guidance literature:

With methyl iodide; palladium dichloride; at 60 ℃; for 2.5h;

DOI:10.1016/S0022-328X(03)00254-7

Reference yield: 53.0%

tert-butyl(dimethyl)(phenylseleno)silane (72726-46-6) → tert-butyldimethylsilyl iodide (72726-45-5)

Guidance literature:

With iodine;

DOI:10.1021/jo00320a012

Reference yield:

tert-butyl(dimethyl)(phenylseleno)silane (72726-46-6) → diphenyl diselenide (1666-13-3) + tert-butyldimethylsilyl iodide (72726-45-5)

Guidance literature:

With iodine; In acetonitrile;

DOI:10.1021/jo01293a034

upstream raw materials:

tert-butyl(dimethyl)(phenylseleno)silane

tert-butyldimethylsilane

tert-butyldimethylsilyl chloride

Downstream raw materials:

tert-butyl(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethylsilane

Diphenylacetaldehyde

tert-Butyl-(2-iodo-1,2-diphenyl-ethoxy)-dimethyl-silane

tert-Butyl-(2-iodo-1,2-diphenyl-ethoxy)-dimethyl-silane

Refernces

• 1、 Pearson, Anthony J.,Hsu, Shih-Ying. "Ester-Directed Alkene Functionalization. A Potential Approach to Trichothecene Synthesis". . p. 2505 - 2511. Retrieved 2007/10/02.
• 2、 Detty, Michael R.. "Electrophilic Conversion of Oxiranes to Allylic Alcohols with tert-Butyldimethylsilyl Iodide". . p. 924 - 926. Retrieved 2007/10/02.