Lithium metaborate

Base Information

• Chemical Name: Lithium metaborate
• CAS No.: 13453-69-5
• Molecular Formula: LiBO2
• Molecular Weight: 49.7508
• Hs Code.: 2840200000
• Mol file: 13453-69-5.mol

Synonyms:lithium,oxido(oxo)borane;Boric acid lithium salt;Lithium metaborate;

Chemical Property of Lithium metaborate

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 845 °C(lit.)
• PSA: 40.13000
• Density: 1.4 g/cm³
• LogP: -0.88610

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Lithium metaborate

There total 5 articles about Lithium metaborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Li(1+)*{(C6H5)B(OH)3}(1-)=Li{(C6H5)B(OH)3} → lithium metaborate (13453-69-5) + water (7732-18-5) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

thermal decompn. in air at 115°C and in N2 atmosphere at 120°C;

Reference yield:

Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O → lithium metaborate (13453-69-5) + water (7732-18-5)

Guidance literature:

With oxygen; byproducts: CO2; oxisative decompn. on heating;

DOI:10.1039/jr9610000910

Reference yield:

cobalt lithium orthoborate → cobalt(II,III) oxide + lithium metaborate (13453-69-5)

Guidance literature:

In neat (no solvent, solid phase); heating in air (800°C);

upstream raw materials:

water

selenium

lithium hydroxide

Downstream raw materials:

water

lithium tetramethanolatoborate

Refernces

• 1、 Chen, Kang,Ouyang, Liuzhang,Zhong, Hao,Liu, Jiangwen,Wang, Hui,Shao, Huaiyu,Zhang, Yao,Zhu, Min. "Converting H+ from coordinated water into H- enables super facile synthesis of LiBH4". . p. 4380 - 4387. Retrieved 2019/08/22.