p-Chlorobenzyl-p-chlorophenyl sulfone

Base Information

• Chemical Name: p-Chlorobenzyl-p-chlorophenyl sulfone
• CAS No.: 7082-99-7
• Molecular Formula: C13H10 Cl2 O2 S
• Molecular Weight: 301.1883
• European Community (EC) Number: 806-361-8
• NSC Number: 404953,56973
• UNII: 778U6079DF
• DSSTox Substance ID: DTXSID9042257
• Nikkaji Number: J1.493.019A
• Wikidata: Q27266560
• Mol file: 7082-99-7.mol

Synonyms:7082-99-7;p-Chlorobenzyl-p-chlorophenyl sulfone;CHLORBENSIDE-SULFONE;Chlorbenside sulfone;1-chloro-4-[(4-chlorophenyl)sulfonylmethyl]benzene;p-Chlorobenzyl p-chlorophenyl sulfone;NSC-56973;778U6079DF;NSC-404953;Sulfone, p-chlorobenzyl p-chlorophenyl;Benzene, 1-chloro-4-(((4-chlorophenyl)methyl)sulfonyl)-;Benzene, 1-chloro-4-[[(4-chlorophenyl)methyl]sulfonyl]-;UNII-778U6079DF;AI3-14296;NCIOpen2_007461;DTXSID9042257;SCHEMBL23803109;NSC56973;NSC 56973;NSC404953;NSC 404953;(4-Chlor-benzyl)-(4-chlorphenyl)-sulfon;1-Chloro-4-((4-chlorobenzyl)sulfonyl)benzene;CHLOROBENZYL-P-CHLOROPHENYL SULFONE, P-;CHLOROBENZYL-P-CHLOROPHENYL SULPHONE, P-;Q27266560;Chlorbenside sulfone, PESTANAL(R), analytical standard

Chemical Property of p-Chlorobenzyl-p-chlorophenyl sulfone

Chemical Property:

• Vapor Pressure: 1.52E-08mmHg at 25°C
• Boiling Point: 469.7°C at 760 mmHg
• Flash Point: 237.9°C
• PSA: 42.52000
• Density: 1.395g/cm³
• LogP: 5.04810
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 299.9778561
• Heavy Atom Count: 18
• Complexity: 348

Purity/Quality:

99% ^*data from raw suppliers

Chlorbenside sulfone PESTANAL ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 2130380
• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1CS(=O)(=O)C2=CC=C(C=C2)Cl)Cl
• Uses: Chlorbenside Sulfone is a pesticide residue in foods. A synthetic organic insecticide.

Technology Process of p-Chlorobenzyl-p-chlorophenyl sulfone

There total 4 articles about p-Chlorobenzyl-p-chlorophenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

4-Chlorobenzylcobaloxime + 4-chlorobenzenesulfonyl chloride (98-60-2) → 1,2-bis(4-chlorophenyl)ethane (5216-35-3) + (4-chloro-benzyl)-(4-chloro-phenyl)-sulfone (7082-99-7) + Butane-2,3-dione O-(4-chloro-benzyl)-oxime oxime (105553-73-9)

Guidance literature:

With pyridine; 4-chlorobenzenesulfonyl chloride; In dichloromethane; at 0 ℃; for 2h; Irradiation;

Reference yield:

sodium p-chlorobenzenesulphinate (14752-66-0) + 4-chlorobenzyl bromide (622-95-7) → (4-chloro-benzyl)-(4-chloro-phenyl)-sulfone (7082-99-7)

Guidance literature:

With ethanol;

Reference yield:

chlorbenside (103-17-3) → (4-chloro-benzyl)-(4-chloro-phenyl)-sulfone (7082-99-7)

Guidance literature:

With dihydrogen peroxide; acetic acid;

DOI:10.1017/S1092852900022045

upstream raw materials:

chlorbenside

sodium p-chlorobenzenesulphinate

4-chlorobenzyl bromide

4-chlorobenzenesulfonyl chloride

Downstream raw materials:

4-(4-chloro-benzenesulfonyl)-4-(4-chloro-phenyl)-heptanedinitrile

1-Chloro-4-[1-[(4-chlorophenyl)sulfonyl]-5-(methylsulfonyl)pentyl]benzene

Refernces

• 1、 Gupta, B. Dass,Roy, Maheswar,Roy, Sujit,Kumar, Manoj,Das, Indira. "Homolytic Displacement at Saturated Carbon in Organocobalamines. Part 4". . p. 537 - 543. Retrieved 2007/10/02.