titanium(4+) isodecan-1-olate

Base Information

• Chemical Name: titanium(4+) isodecan-1-olate
• CAS No.: 71832-75-2
• Molecular Formula: C₆H₁₂
• Molecular Weight: 84.1613
• Mol file: 71832-75-2.mol

Synonyms:Isodecanol,titanium(4+) salt (9CI)

Chemical Property of titanium(4+) isodecan-1-olate

Chemical Property:

• Vapor Pressure: 0.0365mmHg at 25°C
• Boiling Point: 213.4°C at 760 mmHg
• Flash Point: 87.1°C
• PSA: 92.24000
• LogP: 13.65400

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of titanium(4+) isodecan-1-olate

There total 62 articles about titanium(4+) isodecan-1-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 2-methyl-2-pentene (625-27-4) + 3-hexene (592-47-2) + trans-2-hexene (4050-45-7) + (E)-4-methylpent-2-ene (674-76-0)

Guidance literature:

(C₃H₅)2AlCl; Ni(C₆H₇O₂)2; triphenylphosphine; Further byproducts given. Title compound not separated from byproducts;

Reference yield: 25.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 2-methyl-2-pentene (625-27-4) + 2-Methyl-1-pentene (763-29-1) + trans-2-hexene (4050-45-7) + (E)-4-methylpent-2-ene (674-76-0)

Guidance literature:

(C₃H₅)2AlCl; Ni(C₆H₇O₂)2; triphenylphosphine; Further byproducts given. Title compound not separated from byproducts;

Reference yield: 13.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 2-methyl-2-pentene (625-27-4) + 2-Methyl-1-pentene (763-29-1) + 3-hexene (592-47-2) + trans-2-hexene (4050-45-7) + (Z)-4-methyl-2-pentene (691-38-3) + (E)-4-methylpent-2-ene (674-76-0)

Guidance literature:

(C₃H₅)2AlCl; Ni(C₅H₇O₂)2; triphenylphosphine; Product distribution;

upstream raw materials:

Methyl isobutyl carbinol

1-hexene

4-methyl-1,3-pentadiene

2-methyl-3-pentanol

Refernces

• 1、 Alawisi, Hussah,Arman, Hadi D.,Tonzetich, Zachary J.. "Catalytic Hydrogenation of Alkenes and Alkynes by a Cobalt Pincer Complex: Evidence of Roles for Both Co(I) and Co(II)". . p. 1062 - 1070. Retrieved 2021/04/09.
• 2、 Wang, Yulei,Qin, Chuan,Jia, Xiangqing,Leng, Xuebing,Huang, Zheng. "An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1-Alkenes to trans-2-Alkenes". supporting information. p. 1614 - 1618. Retrieved 2017/02/05.