(+)-Fenchone

Base Information Edit

Chemical Name:(+)-Fenchone
CAS No.:4695-62-9
Deprecated CAS:1212434-47-3,1220042-99-8,1276016-83-1,1310540-18-1,1325056-25-4,1822336-36-6,2180109-09-3,2308490-83-5,2649107-63-9,1276016-83-1,1310540-18-1,1325056-25-4
Molecular Formula:C10H16 O
Molecular Weight:152.236
Hs Code.:29142990
European Community (EC) Number:225-160-0
UNII:S436YKU51N
DSSTox Substance ID:DTXSID60858862
Nikkaji Number:J108.019I
Wikidata:Q27067421
Metabolomics Workbench ID:49970
Mol file:4695-62-9.mol

Synonyms:(+)-1,3,3-Trimethyl-2-norbornanone;(+)-Fenchone;(+)-Fenchone, 98%;(1S)-(+)-fenchone;1,3,3-Trimethyl-2-norbornanone, D-;1,3,3-Trimethyl-2-norcamphanone, D-;2-Norbornanone, 1,3,3-trimethyl-, (1R,4S)-(+)-;2-Norbornanone, 1,3,3-trimethyl-, (1S,4R)-(+)-;225-160-0;4695-62-9;d-1,3,3-Trimethyl-2-norbornanone;d-1,3,3-Trimethyl-2-norcamphanone;D-FENCHONE, 77%;EINECS 225-160-0;FEMA No. 2479;fenchone, (1S)-isomer;Fenchone, D-;D-FENCHONE;(1S,4R)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-one;(1S,4R)-fenchone;(1S)-fenchone;(+)-2-fenchanone;(+)-fenchan-2-one;(1S,4R)-2-fenchanone;(1S,4R)-fenchan-2-one;UNII-S436YKU51N;(1S,4R)-(+)-fenchone;S436YKU51N;(1S,4R)-(+)-2-fenchanone;(1S,4R)-(+)-fenchan-2-one;2-Fenchanone, D-;d-Fenchone (natural);Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1S,4R)-;(1R)-1,3,3-Trimethylbicyclo(2.2.1)heptan-2-one;(1S)-1,3,3-Trimethylbicyclo(2.2.1)heptan-2-one;(1S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one;(1R,4S)-2,2,4-trimethylbicyclo[2.2.1]heptan-3-one;1,3,3-Trimethylbicyclo(2.2.1)heptan-2-one, (1S)-;Bicyclo(2.2.1)heptan-2-one, 1,3,3-trimethyl-, (1S)-;Bicyclo(2.2.1)heptan-2-one, 1,3,3-trimethyl-, (1S,4R)-;(1s)-1,3,3-trimethyl-norbornan-2-one;1,3,3 - trimethylnorbornan - 2 - one;D-FENCHONE [MI];2-Norbornanone, 1,3,3-trimethyl-, (1R,4S)-()-;D-FENCHONE [FHFI];FENCHONE [WHO-DD];2-Norbornanone, 1,3,3-trimethyl-, (1S,4R)-(-)-;Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1S)-;FENCHONE, (+)-;(1S) - 1,3,3 - trimethylbicyclo(2.2.1)heptan - 2 - one;CHEBI:165;SCHEMBL856607;(+)-FENCHONE [FCC];DTXSID60858862;(+)-Fenchone, analytical standard;MFCD00070689;AKOS015903221;CS-W016296;HY-W015580;(+)-Fenchone 100 microg/mL in Methanol;D90638;EN300-112063;Q27067421;(+)-Fenchone, primary pharmaceutical reference standard;Z1255427411;(+)-Fenchone, purum, >=98.0% (sum of enantiomers, GC);Bicyclo[2.2.1]heptan-2-one,1,3,3-trimethyl-,(1S,4R)-

Suppliers and Price of (+)-Fenchone

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(+)-Fenchone
5g
$ 95.00

TRC
(+)-Fenchone
1g
$ 65.00

TCI Chemical
(+)-Fenchone >98.0%(GC)
25mL
$ 48.00

Sigma-Aldrich
(+)-Fenchone purum,≥98.0%(sumofenantiomers,GC)
100 mL
$ 141.00

Sigma-Aldrich
(+)-Fenchone purum, ≥98.0% (sum of enantiomers, GC)
100ml-f
$ 133.00

Sigma-Aldrich
(+)-Fenchone analyticalstandard
5 mL
$ 122.00

Sigma-Aldrich
(+)-Fenchone analytical standard
5ml-f
$ 118.00

Sigma-Aldrich
(+)-Fenchone analytical standard
25ml-f
$ 470.00

Sigma-Aldrich
(+)-Fenchone primary reference standard
100mg
$ 200.00

Sigma-Aldrich
(+)-Fenchone analyticalstandard
1 mL
$ 40.00

Total 25 raw suppliers

Chemical Property of (+)-Fenchone Edit

Chemical Property:

Vapor Pressure:0.463mmHg at 25°C
Melting Point:5-6 °C(lit.)
Refractive Index:n20/D 1.461(lit.)
Boiling Point:192-194 °C(lit.)
Flash Point:52.8°C
PSA：17.07000
Density:0.982g/cm³
LogP:2.40170
Storage Temp.:2-8°C
Water Solubility.:2.147g/L(25 oC)
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:217

Purity/Quality:

98% ^*data from raw suppliers

(+)-Fenchone ^*data from reagent suppliers

Safty Information:

Pictogram(s): R10:Flammable.;
Hazard Codes:R10:Flammable.;
Statements: 10
Safety Statements: 23-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC(C2)(C1=O)C)C
Isomeric SMILES:C[C@]12CC[C@H](C1)C(C2=O)(C)C
Description d-Fenchone has a camphor-like odor, powerful and sweet, and a warm, somewhat bitter, burning taste. d-Fenchone is isolated from cedarleaf oil (thuja oil).
Uses Reference Standard in the analysis of herbal medicinal products As flavor in foods; in perfumes.

Technology Process of (+)-Fenchone

There total 31 articles about (+)-Fenchone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 470-08-6,512-13-0,1632-73-1,2217-02-9,14575-74-7,22627-95-8,36386-49-9,36386-50-2,64439-31-2
D-fenchyl alcohol

: 4695-62-9,126-21-6
fenchone

Guidance literature:: With C₄₄H₆₆O₈P₄Pd₂; methyl vinyl ketone; In water; toluene; at 105 ℃; for 16h; chemoselective reaction; Inert atmosphere;
DOI:10.1002/cctc.201601261

Reference yield: 85.0%

: 470-08-6
(-)-β-fenchol

: 4695-62-9,126-21-6
fenchone

Guidance literature:: With oxone; C₁₈H₁₇IN₂O₇PolS^(1-)*Na⁽¹⁺⁾; tetra(n-butyl)ammonium hydrogensulfate; In acetonitrile; at 70 ℃; for 3h; Reagent/catalyst; Solvent; Sealed tube; Green chemistry;
DOI:10.1039/c9gc02605c